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• W2767005290 abstract "Nanocelluloses isolated from agricultural biomass have attracted increasing attention as emerging renewable nanomaterials as well as ways to valorize these otherwise underutilized wastes from the food production system while alleviate the negative impact on our environment. Rice straw represents the largest quantity crop residue from the highest value crop in the world and contains ca. 40 % cellulose, similar to wood. Depending on the methods of isolation and derivation, a range of nanocelluloses with different surface chemistries and geometries have been facilely derived from rice straw via H2SO4 hydrolysis, TEMPO oxidation, and mechanical defibrillation, etc. These nanocelluloses, i.e., short and rigid cellulose nanocrystals (CNCs) as well as long and flexible cellulose nanofibrils (CNFs), exhibit significantly different crystalline and thermal characteristics and behaviors in liquids and from drying. These nanocelluloses self-assemble, under controlled freezing and freeze-drying, into tunable morphologies ranging from continuous nanofibers to sub-micron fibers, macroscopic films, to porous mass with intriguing amphiphilicity. This chapter focuses on self-assembling of rice straw nanocelluloses into fibrous structures. These diverse nanocelluloses and their self-assembled fibrous structures from a single agriculture biomass, rice straw, demonstrate the significance of processes in generating nanocelluloses and drying and how they offer precise control on creating the desired characteristics of nanocelluloses, nanoscale and micro-scale fibrous structures for potential applications." @default.
• W2767005290 created "2017-11-10" @default.
• W2767005290 creator A5025187052 @default.
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• W2767005290 date "2017-01-01" @default.
• W2767005290 modified "2023-10-17" @default.
• W2767005290 title "Rice Straw Nanocelluloses: Process-Linked Structures, Properties, and Self-Assembling into Ultra-Fine Fibers" @default.
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• W2767005290 doi "https://doi.org/10.1021/bk-2017-1251.ch007" @default.
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