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• W2767009591 abstract "We investigate the impact of peripheral cyano functionalization of the previously well-studied 2H-tetraphenylporphyrin (2HTPP) by scanning tunneling microscopy (STM) and density functional theory (DFT). The adsorption behavior of 2H-tetrakis(p-cyano)-phenylporphyrin (2HTCNPP) is studied at room temperature and at 80 K on Cu(111) and Ag(111). Interestingly, the cyano-functionalized porphyrins tend to form isolated 1D chains on Cu(111), in particular after mild annealing at 350 K. The individual 2HTCNPPs as well as the formed chains are oriented along the main crystallographic directions of the Cu(111) substrate due to a strongly attractive and site-specific interaction between the iminic nitrogens of the 2HTCNPP and Cu substrate atoms. The linking within the 1D molecular chains is realized by Cu adatoms as evidenced by comparison of STM and DFT. In contrast, on Ag(111) the molecules assemble into 2D supramolecular layers with long-range order and a square unit cell, stabilized by molecule–molecule interactions. The orientation of the molecules with respect to the unit cell lattice vectors leads to organizational chirality. By codeposition of cobalt, the porphyrin molecules are metalated at room temperature. We did not observe any evidence for metal–organic network formation on Ag(111), even after varying the deposition parameters or the order of metal and porphyrin deposition. Our study shows that cyano functionalization of porphyrins can give rise to novel and unique self-assembled structures like 1D molecular chains without any cross-connections via adatom linking." @default.
• W2767009591 created "2017-11-10" @default.
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• W2767009591 date "2017-11-16" @default.
• W2767009591 modified "2023-10-16" @default.
• W2767009591 title "Adsorption Behavior of a Cyano-Functionalized Porphyrin on Cu(111) and Ag(111): From Molecular Wires to Ordered Supramolecular Two-Dimensional Aggregates" @default.
• W2767009591 cites W1177071998 @default.
• W2767009591 cites W1963549289 @default.
• W2767009591 cites W1964908369 @default.
• W2767009591 cites W1965542836 @default.
• W2767009591 cites W1969510290 @default.
• W2767009591 cites W1970257075 @default.
• W2767009591 cites W1970565878 @default.
• W2767009591 cites W1979087321 @default.
• W2767009591 cites W1979170599 @default.
• W2767009591 cites W1980679994 @default.
• W2767009591 cites W1980770266 @default.
• W2767009591 cites W1981368803 @default.
• W2767009591 cites W1982911623 @default.
• W2767009591 cites W1983213989 @default.
• W2767009591 cites W1983602684 @default.
• W2767009591 cites W1987032187 @default.
• W2767009591 cites W1997638099 @default.
• W2767009591 cites W2001237575 @default.
• W2767009591 cites W2004124981 @default.
• W2767009591 cites W2007988830 @default.
• W2767009591 cites W2015391752 @default.
• W2767009591 cites W2015761085 @default.
• W2767009591 cites W2023391441 @default.
• W2767009591 cites W2023715488 @default.
• W2767009591 cites W2032054611 @default.
• W2767009591 cites W2032861206 @default.
• W2767009591 cites W2038296267 @default.
• W2767009591 cites W2047205370 @default.
• W2767009591 cites W2051050585 @default.
• W2767009591 cites W2067707236 @default.
• W2767009591 cites W2068632999 @default.
• W2767009591 cites W2076325692 @default.
• W2767009591 cites W2077638937 @default.
• W2767009591 cites W2082266156 @default.
• W2767009591 cites W2083458058 @default.
• W2767009591 cites W2085511517 @default.
• W2767009591 cites W2087585288 @default.
• W2767009591 cites W2087810283 @default.
• W2767009591 cites W2089944057 @default.
• W2767009591 cites W2090380475 @default.
• W2767009591 cites W2091244978 @default.
• W2767009591 cites W2092157292 @default.
• W2767009591 cites W2095395511 @default.
• W2767009591 cites W2096747776 @default.
• W2767009591 cites W2097021974 @default.
• W2767009591 cites W2101850500 @default.
• W2767009591 cites W2108541397 @default.
• W2767009591 cites W2110062472 @default.
• W2767009591 cites W2112984572 @default.
• W2767009591 cites W2120145199 @default.
• W2767009591 cites W2129939050 @default.
• W2767009591 cites W2131781277 @default.
• W2767009591 cites W2136607965 @default.
• W2767009591 cites W2136617937 @default.
• W2767009591 cites W2142224432 @default.
• W2767009591 cites W2146821070 @default.
• W2767009591 cites W2147592303 @default.
• W2767009591 cites W2150705598 @default.
• W2767009591 cites W2151110804 @default.
• W2767009591 cites W2152327709 @default.
• W2767009591 cites W2156476578 @default.
• W2767009591 cites W2164777227 @default.
• W2767009591 cites W2288316925 @default.
• W2767009591 cites W2308580910 @default.
• W2767009591 cites W2316044636 @default.
• W2767009591 cites W2316445734 @default.
• W2767009591 cites W2316883415 @default.
• W2767009591 cites W2318784357 @default.
• W2767009591 cites W2329552138 @default.
• W2767009591 cites W2333916742 @default.
• W2767009591 cites W2409079334 @default.
• W2767009591 cites W2535498216 @default.
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• W2767009591 doi "https://doi.org/10.1021/acs.jpcc.7b08382" @default.
• W2767009591 hasPublicationYear "2017" @default.
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