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- W276706189 abstract "The solid-state structure of the title compound, [Cu(C19H13F2N2)(C5H9N)2], shows that the CuI centre adopts a distorted tetrahedral coordination geometry, being coordinated by two N atoms of the 6-aminofulvene-2-aldimine (AFA) chelating ligand and by the bridgehead C atoms of the two isocyanide ligands. The cyclopentadienyl and imine components of the AFA ligand are approximately coplanar, with an angle between the planes of 5.00 (3)°. The Cu atom lies 0.6460 (3) Å above the imine plane defined by the N and C atoms of the seven-membered metallocycle. There is also an uncommon C—H⋯Cu anagostic interaction, with an intramolecular Cu⋯H distance of 2.67 Å, which is less than the sum of the van der Waals radii." @default.
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- W276706189 date "2011-06-04" @default.
- W276706189 modified "2023-10-16" @default.
- W276706189 title "Bis(<i>tert</i>-butyl isocyanide-κ<i>C</i>)[4-fluoro-<i>N</i>-({2-[<i>N</i>-(4-fluorophenyl)carboximidoyl]cyclopenta-2,4-dien-1-ylidene}methyl)anilinido-κ<sup>2</sup><i>N</i>,<i>N</i>′]copper(I)" @default.
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- W276706189 doi "https://doi.org/10.1107/s010827011101972x" @default.
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