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- W2767073722 abstract "A series of diiron complexes has been prepared and structurally characterized. Treatment of the complex (μ-SCH2CH2S-μ)Fe2(CO)6 (1) or [μ-SC6H3(CH3)S-μ]Fe2(CO)6 (2) with a monophosphine ligand, Ph2PR [R = CH3, CH(CH3)2, CH2CHCH2] in the presence of Me3NO·2H2O afforded the complexes (μ-SCH2CH2S-μ)Fe2(CO)5(Ph2PR) [R = CH3, 3; CH(CH3)2, 4; CH2CHCH2, 5] and [μ-SC6H3(CH3)S-μ]Fe2(CO)5(Ph2PR) [R = CH3, 6; CH(CH3)2, 7; CH2CHCH2, 8] in 66–92% yields. The complexes 3–8 were characterized by elemental analysis, spectroscopy and single crystal X-ray diffraction analysis." @default.
- W2767073722 created "2017-11-10" @default.
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- W2767073722 date "2018-01-01" @default.
- W2767073722 modified "2023-09-26" @default.
- W2767073722 title "Alkyldiphenylphosphine substituted diiron ethanedithiolate or toluenedithiolate complexes" @default.
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- W2767073722 doi "https://doi.org/10.1016/j.poly.2017.10.017" @default.
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