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- W2767086460 abstract "As a member of the lead-halide perovskite family, inorganic perovskite CsPbBr3 exhibits excellent optical and electrical properties with higher stability to the environment. However, former efforts to obtain large-size CsPbBr3 single crystals with satisfactory quality using low temperature solution methods reached limited results. In this work, we have studied the growth of CsPbBr3 crystals using the antisolvent vapor-assisted crystallization (AVC) method. By adjusting the mole ratio of PbBr2 and CsBr, the phase diagram of the final products is acquired. Five regions are identified, including the Cs4PbBr6 single phase region, Cs4PbBr6 and CsPbBr3 two phases region, CsPbBr3 single phase region, CsPbBr3 and PbBr2·2[(CH3)2SO] metastable two phases region, and CsPbBr3 and PbBr2·2[(CH3)2SO] two phases region. Three methods are adopted to improve the size and crystalline quality of CsPbBr3. The growth rate is effectively tailored by diluting the antisolvent MeOH solution using DMSO to reduce the MeOH vapor pres..." @default.
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- W2767086460 date "2017-10-25" @default.
- W2767086460 modified "2023-10-15" @default.
- W2767086460 title "Centimeter-Sized Inorganic Lead Halide Perovskite CsPbBr<sub>3</sub> Crystals Grown by an Improved Solution Method" @default.
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- W2767086460 doi "https://doi.org/10.1021/acs.cgd.7b01086" @default.
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