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• W2767096129 abstract "Diaddition of alkenyllithium to 1,2-diones induce dianionic oxy-Cope rearrangements. As 1,2-diones some 1,2-diarylethane-1,2-diones were treated with (4,5-dihydrofuran-2-yl)lithium. The reaction, which took place at -78 °C, stereoselctively afforded meso-3,3'-coupled bis(tetrahydrofurans), which, in contrast to their 2,2' counterparts, have so far hardly been investigated. Two of the reaction products were characterized by crystal structure analyses. Subsequent intramolecular aldol addition gave a highly substituted octahydro-2H-cyclopenta[1,2-b:4,3-b']difuran, whose constitution and relative configuration were determined by NMR including NOE measurements." @default.
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• W2767096129 date "2017-12-14" @default.
• W2767096129 modified "2023-09-24" @default.
• W2767096129 title "Dianionic Oxy-Cope Rearrangement with Benzil Derivatives: meso -Selective 3,3-Coupling of Two Tetrahydrofuran Moieties" @default.
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• W2767096129 doi "https://doi.org/10.1002/ejoc.201701397" @default.
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