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- W2767163821 abstract "Abstract The dodecyle benzene sulphonic acid doped polyaniline (DBSA doped PANI) and dodecyle benzene sulphonic acid doped polyaniline-TiO 2 (DBSA doped PANI-TiO 2 ) nanocomposite were synthesized via in situ oxidative polymerization and characterized by Fourier transform infrared (FTIR) spectroscopy, ThermoGravimetric/differential ThermoGravimetric analysis (TGA/DTA), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). The protective properties of epoxy/DBSA doped PANI and epoxy/DBSA doped PANI-TiO 2 coated mild steel were evaluated by electrochemical impedance spectroscopy (EIS) in NaCl 3.5 wt% at 65 °C with and without cathodic protection (CP). Cathodic protection was applied at − 500, − 750, − 1000, − 1250 and − 1500 mV vs. Ag/AgCl. The application of cathodic protection at more negative potentials than − 750 mV affected the performance of the both coatings causing the decreasing of coating resistance (R coat ). The coating resistance of epoxy/DBSA doped PANI and epoxy/DBSA doped PANI-TiO 2 are in the order of 1 × 10 4 Ω cm 2 and 1 × 10 5 Ω cm 2 , respectively. Accordingly, the coating capacitance and water uptake of epoxy/DBSA doped PANI is greater than epoxy/DBSA doped PANI-TiO 2 at whole applied potentials. The protective performance of epoxy/DBSA doped PANI coating is improved in the presence of TiO 2 nanoparticles under different cathodic potentials." @default.
- W2767163821 created "2017-11-10" @default.
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- W2767163821 date "2017-12-01" @default.
- W2767163821 modified "2023-10-13" @default.
- W2767163821 title "Electrochemical impedance spectroscopy evaluation on the protective properties of epoxy/DBSAdoped polyaniline-TiO 2 nanocomposite coated mild steel under cathodic polarization" @default.
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- W2767163821 doi "https://doi.org/10.1016/j.surfcoat.2017.10.043" @default.
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