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- W2767202260 endingPage "16043" @default.
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- W2767202260 abstract "A new approach for the synthesis of 1,4-dicarbonyl compounds is reported. Chemoselective activation of amide carbonyl functionality and subsequent umpolung via N-oxide addition generates an electrophilic enolonium species that can be coupled with a wide range of nucleophilic enolates. The method conveys broad functional group tolerance on both components, does not suffer from formation of homocoupling byproducts and avoids the use of transition metal catalysts." @default.
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- W2767202260 date "2017-11-03" @default.
- W2767202260 modified "2023-10-12" @default.
- W2767202260 title "Chemoselective Intermolecular Cross-Enolate-Type Coupling of Amides" @default.
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- W2767202260 doi "https://doi.org/10.1021/jacs.7b08813" @default.
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