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• W2767431906 abstract "Temperature dependences are compared for 1H and 13C NMR 1/T1 curves relaxation rates in three imidazolium-based ionic liquids (ILs), namely, in [bmim]PF6, [bmim]BF4, and [emim]CH3COO. 13C curves show alike behavior for all three ILs and follow a well-known Bloembergen-Pound-Purcell (BPP) equation. On the contrary, an essential part of 1H curves differ strongly from corresponding 13C ones and also have different shapes for different ILs. For the first time, we have detected the specific, two-maximum shape of 1H relaxation curve for hydrogen atom of C(2)H group of the [emim]CH3COO. Assuming that this maximum reflects the correlated rotation of several adjoining ion pairs, we have tried to destroy this rotation by addition of glycerol to the [emim]CH3COO. The second, high-temperature maximum has disappeared in the [emim]CH3COO–glycerol mixture, and this fact confirms our assumption. Copyright © 2017 John Wiley & Sons, Ltd." @default.
• W2767431906 created "2017-11-17" @default.
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• W2767431906 date "2017-12-03" @default.
• W2767431906 modified "2023-10-16" @default.
• W2767431906 title "Molecular mobility in several imidazolium-based ionic liquids according to data of¹H and¹³C NMR relaxation" @default.
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• W2767431906 doi "https://doi.org/10.1002/mrc.4681" @default.
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