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- W2767503602 abstract "Metal nanoparticles supported on oxide surfaces form the basis for many industrial catalysts and promise to play an ever-increasing role in future energy and environmental technologies. The chemical potential (μ) of the metal atoms in these particles depends strongly on particle size and support and is an important factor that determines their catalytic properties, including their binding strengths to adsorbed reaction intermediates and their long-term stability against sintering. We present here a method for estimating this chemical potential as a function of particle size for different metal/oxide combinations. We show that this chemical potential for late transition metals is well approximated for a particle of diameter D by μ(D) = [(3γm – Eadh)(1 + Do/D)](2 Vm/D), where γm is the surface energy of the bulk metal, Eadh is the adhesion energy at the bulk metal/oxide interface, and Do is ∼1.5 nm, and Vm is the molar volume of the bulk metal. We further show that Eadh increases with (1) increasing heat of..." @default.
- W2767503602 created "2017-11-17" @default.
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- W2767503602 date "2017-11-14" @default.
- W2767503602 modified "2023-10-17" @default.
- W2767503602 title "Chemical Potential of Metal Atoms in Supported Nanoparticles: Dependence upon Particle Size and Support" @default.
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- W2767503602 doi "https://doi.org/10.1021/acscatal.7b03090" @default.
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