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- W2767505890 endingPage "4832" @default.
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- W2767505890 abstract "Abstract The capability of a polymer to depolymerize, regenerating its original monomer for further polymerization, is very attractive in terms of sustainability. Recently discovered sugar poly(orthoesters) are an important class of glycopolymer. The high sensitivity of the backbone orthoester linkage toward acidolysis provides a valuable model to study the depolymerization. Herein, a sugar poly(orthoester) is shown to be completely depolymerized under acidic conditions. Interestingly, instead of the original monomer, the depolymerization gave a stable cyclic product (1,6‐anhydro glucopyranose) in most cases, which was kinetically and thermodynamically favored. However, this pathway could be inhibited by chemically deactivating a key intermediate and thus favoring the formation of the original monomer. Efficient repolymerizaton of the regenerated monomer is also demonstrated." @default.
- W2767505890 created "2017-11-17" @default.
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- W2767505890 date "2017-11-24" @default.
- W2767505890 modified "2023-10-17" @default.
- W2767505890 title "Complete Depolymerization and Repolymerization of a Sugar Poly(orthoester)" @default.
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- W2767505890 doi "https://doi.org/10.1002/cssc.201701870" @default.
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