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• W2767506253 abstract "Abstract Charge compensation was the effective methods to enhance the luminescence properties of phosphors. In this paper, novel single‐phased orange light emitting Sr 2 Mg 3 P 4 O 15 :Eu 3+ phosphors were prepared by solid state method. The phase purity and luminous characteristics were examined in detail. Meanwhile, three kinds of charge compensation methods (co‐doping the alkali metal R + (R + = Li, Na, and K), substituting Si 4+ for P 5+ and self‐compensation) were employed to solve the charge imbalance problem between Sr 2+ and Eu 3+ . The results showed that emission intensity of Eu 3+ was improved by 1.43 (Li + ), 1.58 (Na + ), 1.53 (K + ), 1.61 (Si 4+ ), and 1.30 (self) times than that of Sr 1.6 Mg 3 P 4 O 15 :0.40Eu 3+ , respectively, and there was no change in the emitting color simultaneously. Furthermore, as the temperature reached at 423 K, the emission intensity increased from 41.67% of Sr 1.6 Mg 3 P 4 O 15 :0.40Eu 3+ to 55.69% (Li + ), 61.62% (Na + ), 58.98% (K + ), 71.15% (Si 4+ ), and 80.59% (self) of that at room temperature. The reasons of those phenomena were the reduction in ion vacancies caused by charge imbalance through the charge compensation process. The specific mechanisms were elaborated in detail. Overall, this research validated that the charge compensation strategies could be severed as the key method to improve the luminescence properties, especially the thermal stability of phosphor." @default.
• W2767506253 created "2017-11-17" @default.
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• W2767506253 date "2017-11-28" @default.
• W2767506253 modified "2023-10-18" @default.
• W2767506253 title "Enhancing emission intensity and thermal stability by charge compensation in Sr₂ Mg₃ P₄ O₁₅ :Eu³⁺" @default.
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• W2767506253 doi "https://doi.org/10.1111/jace.15334" @default.
• W2767506253 hasPublicationYear "2017" @default.
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