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• W2767538437 abstract "Abstract Reactions of a magnesium‐based pinacolatoboryl nucleophile with the electrophilic organoboranes, 9‐BBN and Ph 3 B, provide facile B−B′ single bond formation. Although the Ph 3 B derivative is thermally stable, when heated, the unsymmetrical diborane(5) anion derived from 9‐BBN is found to isomerize to two regioisomeric species via a proposed mechanism involving dehydroboration of the borabicyclo[3.3.1]nonane and syn‐diboration of the resultant alkenyl carbocycle." @default.
• W2767538437 created "2017-11-17" @default.
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• W2767538437 date "2017-11-27" @default.
• W2767538437 modified "2023-10-01" @default.
• W2767538437 title "Magnesium Boryl Reactivity with 9-BBN and Ph₃ B: Rational B−B′ Bond Formation and Diborane Isomerization" @default.
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• W2767538437 doi "https://doi.org/10.1002/anie.201709902" @default.
• W2767538437 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5767756" @default.
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