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- W2767599387 abstract "In this work, we report on the anisotropic growth of α-Fe2O3 nanoslabs which are produced by co-precipitation method with the addition of sucrose. In our previous work, we have argued that such behavior can be related with the chelating agent. Experiments of X-ray diffraction (XRD), high-resolution transmission electronic microscopy (HRTEM) and magnetic measurements as a function of temperature and an applied magnetic field are used to characterize the samples. The HRTEM image of the sample prepared with 10 mmol/l of sucrose consists of faceted-like nanoslabs while that prepared without sucrose exhibits particles with a non-uniform shape. In this way, we can state that both the HRTEM images and the analysis of the XRD patterns show clearly a preferential growth of the [110] crystallographic direction. To strengthen our supposition, besides T- and field-dependence of magnetization are consistent with a superparamagnetic behavior the fit of the (Zero Field Cooling and Field Cooling) ZFC-FC curve for sample grown with 10 mmol/l of sucrose presents a strong increase of the effective anisotropy constant, Keff, which can be related with the increasing of the shape magnetic anisotropy." @default.
- W2767599387 created "2017-11-17" @default.
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- W2767599387 date "2018-03-01" @default.
- W2767599387 modified "2023-10-18" @default.
- W2767599387 title "Anisotropic growth of <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si0011.gif overflow=scroll><mml:mi>α</mml:mi></mml:math>-Fe2O3 nanostructures" @default.
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- W2767599387 doi "https://doi.org/10.1016/j.ceramint.2017.11.068" @default.
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