Matches in SemOpenAlex for { <https://semopenalex.org/work/W2767630216> ?p ?o ?g. }
- W2767630216 endingPage "330" @default.
- W2767630216 startingPage "318" @default.
- W2767630216 abstract "We have developed a laser rapid-prototyping method for the realization of microchannels and nozzles in silicon and nickel chips. A practical application of such microreactors, made by rapid prototyping, is the direct fluorination of organic substrates via microbubbles, a highly exothermic and chemically harsh reaction. By employing optimized laser raster ablation procedures, different channel cross-section shapes could be manufactured with adjustable channel wall angles. Modular compressive chip packaging allowed for safe reactor sealing without permanent chip-to-chip bonding. Fluorine gas was introduced into the microchannels, producing a monodisperse chain of bubbles (diameter ∼200 μm) with the reaction taking place at the gas/liquid interfaces. Successful direct fluorinations of fluoroethylene carbonate were carried out over 107 h at room temperature without noticeable leakage or corrosion. High reaction efficiency and an excellent space–time yield for the four products (4,4-F2EC: trans-F2EC: cis-F2EC: F3EC) was demonstrated (65% F2-usage, 1.41 × 106 mol m−3 h−1). cis- and trans-F2EC have shown great potential as electrolyte additives for increasing the lifetime of lithium ion batteries, and trifluorinated F3EC, with eventually improved characteristics, was for the first time fully characterized, e.g. by NMR spectroscopy." @default.
- W2767630216 created "2017-11-17" @default.
- W2767630216 creator A5005853373 @default.
- W2767630216 creator A5030409288 @default.
- W2767630216 creator A5035919046 @default.
- W2767630216 creator A5049738479 @default.
- W2767630216 creator A5050998328 @default.
- W2767630216 date "2017-12-01" @default.
- W2767630216 modified "2023-10-18" @default.
- W2767630216 title "Laser rapid-prototyping and modular packaging of chip-based microreactors for direct fluorination reactions" @default.
- W2767630216 cites W1462661479 @default.
- W2767630216 cites W1523252906 @default.
- W2767630216 cites W1549402836 @default.
- W2767630216 cites W1884625263 @default.
- W2767630216 cites W1964159572 @default.
- W2767630216 cites W1980501647 @default.
- W2767630216 cites W1981195905 @default.
- W2767630216 cites W1981223815 @default.
- W2767630216 cites W1982378872 @default.
- W2767630216 cites W1983401069 @default.
- W2767630216 cites W1996958456 @default.
- W2767630216 cites W2001086298 @default.
- W2767630216 cites W2009264698 @default.
- W2767630216 cites W2009599553 @default.
- W2767630216 cites W2016560002 @default.
- W2767630216 cites W2019184296 @default.
- W2767630216 cites W2024859618 @default.
- W2767630216 cites W2025985254 @default.
- W2767630216 cites W2027825533 @default.
- W2767630216 cites W2028153555 @default.
- W2767630216 cites W2033024315 @default.
- W2767630216 cites W2037224519 @default.
- W2767630216 cites W2043541345 @default.
- W2767630216 cites W2049695801 @default.
- W2767630216 cites W2063915017 @default.
- W2767630216 cites W2070233450 @default.
- W2767630216 cites W2071011408 @default.
- W2767630216 cites W2086492368 @default.
- W2767630216 cites W2093648767 @default.
- W2767630216 cites W2094735983 @default.
- W2767630216 cites W2094830528 @default.
- W2767630216 cites W2104933105 @default.
- W2767630216 cites W2145536380 @default.
- W2767630216 cites W2146993554 @default.
- W2767630216 cites W2150463882 @default.
- W2767630216 cites W2151447580 @default.
- W2767630216 cites W2151603352 @default.
- W2767630216 cites W2153303960 @default.
- W2767630216 cites W2174657615 @default.
- W2767630216 cites W2179424515 @default.
- W2767630216 cites W2317239150 @default.
- W2767630216 cites W2341727092 @default.
- W2767630216 cites W2398209214 @default.
- W2767630216 cites W2409662911 @default.
- W2767630216 cites W2473599700 @default.
- W2767630216 cites W2593414577 @default.
- W2767630216 cites W2949103322 @default.
- W2767630216 cites W2951381445 @default.
- W2767630216 cites W2952783460 @default.
- W2767630216 doi "https://doi.org/10.1016/j.cherd.2017.10.017" @default.
- W2767630216 hasPublicationYear "2017" @default.
- W2767630216 type Work @default.
- W2767630216 sameAs 2767630216 @default.
- W2767630216 citedByCount "4" @default.
- W2767630216 countsByYear W27676302162018 @default.
- W2767630216 countsByYear W27676302162019 @default.
- W2767630216 countsByYear W27676302162021 @default.
- W2767630216 crossrefType "journal-article" @default.
- W2767630216 hasAuthorship W2767630216A5005853373 @default.
- W2767630216 hasAuthorship W2767630216A5030409288 @default.
- W2767630216 hasAuthorship W2767630216A5035919046 @default.
- W2767630216 hasAuthorship W2767630216A5049738479 @default.
- W2767630216 hasAuthorship W2767630216A5050998328 @default.
- W2767630216 hasConcept C127413603 @default.
- W2767630216 hasConcept C147831808 @default.
- W2767630216 hasConcept C159985019 @default.
- W2767630216 hasConcept C161790260 @default.
- W2767630216 hasConcept C178790620 @default.
- W2767630216 hasConcept C185592680 @default.
- W2767630216 hasConcept C192562407 @default.
- W2767630216 hasConcept C2779154291 @default.
- W2767630216 hasConcept C2780395129 @default.
- W2767630216 hasConcept C42360764 @default.
- W2767630216 hasConcept C45119746 @default.
- W2767630216 hasConcept C56200935 @default.
- W2767630216 hasConcept C78519656 @default.
- W2767630216 hasConceptScore W2767630216C127413603 @default.
- W2767630216 hasConceptScore W2767630216C147831808 @default.
- W2767630216 hasConceptScore W2767630216C159985019 @default.
- W2767630216 hasConceptScore W2767630216C161790260 @default.
- W2767630216 hasConceptScore W2767630216C178790620 @default.
- W2767630216 hasConceptScore W2767630216C185592680 @default.
- W2767630216 hasConceptScore W2767630216C192562407 @default.
- W2767630216 hasConceptScore W2767630216C2779154291 @default.
- W2767630216 hasConceptScore W2767630216C2780395129 @default.
- W2767630216 hasConceptScore W2767630216C42360764 @default.
- W2767630216 hasConceptScore W2767630216C45119746 @default.
- W2767630216 hasConceptScore W2767630216C56200935 @default.