Matches in SemOpenAlex for { <https://semopenalex.org/work/W2767692926> ?p ?o ?g. }
- W2767692926 endingPage "8674" @default.
- W2767692926 startingPage "8664" @default.
- W2767692926 abstract "A catalyst composed of monolayer nonstoichiometric titanate nanosheets (denoted as TN) and Pd clusters is constructed for precise synthesis of cyclohexanone from phenol hydrogenation with high conversion (>99%) and selectivity (>99%) in aqueous media under light irradiation. Experimental and DFT calculation results reveal that the surface exposed acid and basic sites on TN could interact with phenol molecules in a nonplanar fashion via a hexahydroxy hydrogen-bonding ring to form a surface coordination species. This greatly facilitates the adsorption and activation of phenol molecules and suppresses the further hydrogenation of cyclohexanone. Moreover, the surface Pd clusters serve as the active sites for the adsorption and dissociation of hydrogen molecules to provide active H atoms. The synergistic effect of the surface coordination species, TN and Pd clusters remarkably facilitate the high yield of cyclohexanone in photocatalysis. Finally, the possible thermo/photocatalytic mechanisms on Pd/TN are propo..." @default.
- W2767692926 created "2017-11-17" @default.
- W2767692926 creator A5002972480 @default.
- W2767692926 creator A5005665234 @default.
- W2767692926 creator A5016546361 @default.
- W2767692926 creator A5021900458 @default.
- W2767692926 creator A5025705813 @default.
- W2767692926 creator A5032425558 @default.
- W2767692926 creator A5070508690 @default.
- W2767692926 creator A5075843083 @default.
- W2767692926 creator A5080610439 @default.
- W2767692926 date "2017-11-21" @default.
- W2767692926 modified "2023-10-14" @default.
- W2767692926 title "A Pd/Monolayer Titanate Nanosheet with Surface Synergetic Effects for Precise Synthesis of Cyclohexanones" @default.
- W2767692926 cites W1784893460 @default.
- W2767692926 cites W1825489262 @default.
- W2767692926 cites W1971756988 @default.
- W2767692926 cites W1975602749 @default.
- W2767692926 cites W1978042914 @default.
- W2767692926 cites W1979174951 @default.
- W2767692926 cites W1982723682 @default.
- W2767692926 cites W1984807473 @default.
- W2767692926 cites W1990718871 @default.
- W2767692926 cites W1990893700 @default.
- W2767692926 cites W1993332534 @default.
- W2767692926 cites W1996772087 @default.
- W2767692926 cites W1997042037 @default.
- W2767692926 cites W1999112719 @default.
- W2767692926 cites W2000500676 @default.
- W2767692926 cites W2001808040 @default.
- W2767692926 cites W2002244911 @default.
- W2767692926 cites W2006534506 @default.
- W2767692926 cites W2010395719 @default.
- W2767692926 cites W2011899447 @default.
- W2767692926 cites W2014788410 @default.
- W2767692926 cites W2027491539 @default.
- W2767692926 cites W2027781933 @default.
- W2767692926 cites W2028204486 @default.
- W2767692926 cites W2030900854 @default.
- W2767692926 cites W2030952714 @default.
- W2767692926 cites W2033634220 @default.
- W2767692926 cites W2038713651 @default.
- W2767692926 cites W2053923926 @default.
- W2767692926 cites W2054563002 @default.
- W2767692926 cites W2059970891 @default.
- W2767692926 cites W2067802660 @default.
- W2767692926 cites W2069376356 @default.
- W2767692926 cites W2074788342 @default.
- W2767692926 cites W2082379024 @default.
- W2767692926 cites W2083230631 @default.
- W2767692926 cites W2090723112 @default.
- W2767692926 cites W2093475160 @default.
- W2767692926 cites W2095424238 @default.
- W2767692926 cites W2098298646 @default.
- W2767692926 cites W2122151612 @default.
- W2767692926 cites W2122275360 @default.
- W2767692926 cites W2132512431 @default.
- W2767692926 cites W2138391970 @default.
- W2767692926 cites W2146498270 @default.
- W2767692926 cites W2147936809 @default.
- W2767692926 cites W2274321691 @default.
- W2767692926 cites W2322625098 @default.
- W2767692926 cites W2329487580 @default.
- W2767692926 cites W2330540385 @default.
- W2767692926 cites W2335127246 @default.
- W2767692926 cites W2399929481 @default.
- W2767692926 cites W2566574075 @default.
- W2767692926 cites W2574743877 @default.
- W2767692926 cites W2586984935 @default.
- W2767692926 cites W2592892761 @default.
- W2767692926 cites W2605134137 @default.
- W2767692926 cites W4234751417 @default.
- W2767692926 cites W4252112632 @default.
- W2767692926 doi "https://doi.org/10.1021/acscatal.7b03463" @default.
- W2767692926 hasPublicationYear "2017" @default.
- W2767692926 type Work @default.
- W2767692926 sameAs 2767692926 @default.
- W2767692926 citedByCount "65" @default.
- W2767692926 countsByYear W27676929262018 @default.
- W2767692926 countsByYear W27676929262019 @default.
- W2767692926 countsByYear W27676929262020 @default.
- W2767692926 countsByYear W27676929262021 @default.
- W2767692926 countsByYear W27676929262022 @default.
- W2767692926 countsByYear W27676929262023 @default.
- W2767692926 crossrefType "journal-article" @default.
- W2767692926 hasAuthorship W2767692926A5002972480 @default.
- W2767692926 hasAuthorship W2767692926A5005665234 @default.
- W2767692926 hasAuthorship W2767692926A5016546361 @default.
- W2767692926 hasAuthorship W2767692926A5021900458 @default.
- W2767692926 hasAuthorship W2767692926A5025705813 @default.
- W2767692926 hasAuthorship W2767692926A5032425558 @default.
- W2767692926 hasAuthorship W2767692926A5070508690 @default.
- W2767692926 hasAuthorship W2767692926A5075843083 @default.
- W2767692926 hasAuthorship W2767692926A5080610439 @default.
- W2767692926 hasConcept C127413603 @default.
- W2767692926 hasConcept C134132462 @default.
- W2767692926 hasConcept C159985019 @default.
- W2767692926 hasConcept C161790260 @default.