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- W2767700718 abstract "This article introduces a consistent and robust model that predicts interfacial tensions for all microemulsion Winsor types and overall compositions. The model incorporates film bending arguments and Huh's equation and is coupled to phase behavior so that simultaneous tuning of both interfacial tension (IFT) and phase behavior is possible. The oil-water interfacial tension and characteristic length are shown to be related to each other through the hydrophilic-lipophilic deviation (HLD). The phase behavior is tied to the micelle curvatures, without the need for using the net average curvature (NAC). The interfacial tension model is related to solubilization ratios in order to introduce a coupled interfacial tension-phase behavior model for all phase environments. The approach predicts two- and three-phase interfacial tensions and phase behavior (i.e., tie lines and tie triangles) for changes in composition and HLD input parameters, such as temperature, pressure, surfactant structure, and oil equivalent alkane carbon number. Comparisons to experimental data show excellent fits and predictive capability." @default.
- W2767700718 created "2017-11-17" @default.
- W2767700718 creator A5031774759 @default.
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- W2767700718 date "2017-11-15" @default.
- W2767700718 modified "2023-10-14" @default.
- W2767700718 title "Coupled Interfacial Tension and Phase Behavior Model Based on Micellar Curvatures" @default.
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- W2767700718 doi "https://doi.org/10.1021/acs.langmuir.7b03372" @default.
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