FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2767873119> ?p ?o ?g. }

• W2767873119 endingPage "17676" @default.
• W2767873119 startingPage "17667" @default.
• W2767873119 abstract "Recent interest in the valorization of lignin has led to reactions involving the cleavage of strong aromatic C-O bonds. However, few experimental mechanistic studies of these reactions have been published. We report detailed mechanistic analysis of the hydrogenolysis of diaryl ethers catalyzed by the combination of Ni(COD)2 (COD = 1,5-cyclooctadiene) and an N-heterocyclic carbene (NHC). Experiments on the catalytic reaction indicated that NaOt-Bu was necessary for catalysis, but kinetic analysis showed that the base is not involved in the rate-limiting C-O bond cleavage. The resting state of the catalyst is an NHC-Ni(η6-arene) complex. Substitution of the coordinated solvent with diaryl ether allowed isolation of a diaryl ether-bound Ni complex. Rate-limiting C-O bond cleavage occurs to generate a three-coordinate product of oxidative addition, a metallacyclic version of which has been prepared independently. Stoichiometric studies show that arene and phenol products are released following reaction with H2. NaOt-Bu was found to deprotonate the phenol product and to prevent formation of inactive NiI dimers." @default.
• W2767873119 created "2017-11-17" @default.
• W2767873119 creator A5026910964 @default.
• W2767873119 creator A5088865204 @default.
• W2767873119 date "2017-11-21" @default.
• W2767873119 modified "2023-10-18" @default.
• W2767873119 title "Mechanistic Investigations of the Hydrogenolysis of Diaryl Ethers Catalyzed by Nickel Complexes of <i>N</i>-Heterocyclic Carbene Ligands" @default.
• W2767873119 cites W1522459688 @default.
• W2767873119 cites W1970418635 @default.
• W2767873119 cites W1971144082 @default.
• W2767873119 cites W1982267818 @default.
• W2767873119 cites W1982825189 @default.
• W2767873119 cites W1985718302 @default.
• W2767873119 cites W1988338980 @default.
• W2767873119 cites W1998205943 @default.
• W2767873119 cites W1999057729 @default.
• W2767873119 cites W1999725493 @default.
• W2767873119 cites W2003143283 @default.
• W2767873119 cites W2003164407 @default.
• W2767873119 cites W2005960625 @default.
• W2767873119 cites W2006084893 @default.
• W2767873119 cites W2023022618 @default.
• W2767873119 cites W2058484679 @default.
• W2767873119 cites W2062497833 @default.
• W2767873119 cites W2072345868 @default.
• W2767873119 cites W2074166183 @default.
• W2767873119 cites W2078647562 @default.
• W2767873119 cites W2083792909 @default.
• W2767873119 cites W2092409183 @default.
• W2767873119 cites W2094120815 @default.
• W2767873119 cites W2096663178 @default.
• W2767873119 cites W2106157176 @default.
• W2767873119 cites W2116189397 @default.
• W2767873119 cites W2126413606 @default.
• W2767873119 cites W2126571061 @default.
• W2767873119 cites W2166766378 @default.
• W2767873119 cites W2221598455 @default.
• W2767873119 cites W2290853326 @default.
• W2767873119 cites W2307580311 @default.
• W2767873119 cites W2325521630 @default.
• W2767873119 cites W2327415113 @default.
• W2767873119 cites W2330961991 @default.
• W2767873119 cites W2331129062 @default.
• W2767873119 cites W2334886742 @default.
• W2767873119 cites W2340243178 @default.
• W2767873119 cites W2412406229 @default.
• W2767873119 cites W2441647337 @default.
• W2767873119 cites W2485429604 @default.
• W2767873119 cites W2515172260 @default.
• W2767873119 cites W2523125801 @default.
• W2767873119 cites W2523846442 @default.
• W2767873119 cites W2553669615 @default.
• W2767873119 cites W2624022514 @default.
• W2767873119 cites W2951136067 @default.
• W2767873119 doi "https://doi.org/10.1021/jacs.7b10537" @default.
• W2767873119 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29116776" @default.
• W2767873119 hasPublicationYear "2017" @default.
• W2767873119 type Work @default.
• W2767873119 sameAs 2767873119 @default.
• W2767873119 citedByCount "76" @default.
• W2767873119 countsByYear W27678731192018 @default.
• W2767873119 countsByYear W27678731192019 @default.
• W2767873119 countsByYear W27678731192020 @default.
• W2767873119 countsByYear W27678731192021 @default.
• W2767873119 countsByYear W27678731192022 @default.
• W2767873119 countsByYear W27678731192023 @default.
• W2767873119 crossrefType "journal-article" @default.
• W2767873119 hasAuthorship W2767873119A5026910964 @default.
• W2767873119 hasAuthorship W2767873119A5088865204 @default.
• W2767873119 hasConcept C155647269 @default.
• W2767873119 hasConcept C161790260 @default.
• W2767873119 hasConcept C178790620 @default.
• W2767873119 hasConcept C181886296 @default.
• W2767873119 hasConcept C185592680 @default.
• W2767873119 hasConcept C2777164566 @default.
• W2767873119 hasConcept C2777702071 @default.
• W2767873119 hasConcept C2778092639 @default.
• W2767873119 hasConcept C2780407432 @default.
• W2767873119 hasConcept C3044715 @default.
• W2767873119 hasConcept C65024703 @default.
• W2767873119 hasConcept C71240020 @default.
• W2767873119 hasConcept C94882840 @default.
• W2767873119 hasConceptScore W2767873119C155647269 @default.
• W2767873119 hasConceptScore W2767873119C161790260 @default.
• W2767873119 hasConceptScore W2767873119C178790620 @default.
• W2767873119 hasConceptScore W2767873119C181886296 @default.
• W2767873119 hasConceptScore W2767873119C185592680 @default.
• W2767873119 hasConceptScore W2767873119C2777164566 @default.
• W2767873119 hasConceptScore W2767873119C2777702071 @default.
• W2767873119 hasConceptScore W2767873119C2778092639 @default.
• W2767873119 hasConceptScore W2767873119C2780407432 @default.
• W2767873119 hasConceptScore W2767873119C3044715 @default.
• W2767873119 hasConceptScore W2767873119C65024703 @default.
• W2767873119 hasConceptScore W2767873119C71240020 @default.
• W2767873119 hasConceptScore W2767873119C94882840 @default.
• W2767873119 hasFunder F4320338292 @default.
• W2767873119 hasIssue "48" @default.
• W2767873119 hasLocation W27678731191 @default.

• next