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- W2768215790 abstract "Ti3[Al1−δCuδ]C2 MAX phase solid solutions have been synthesized by sintering compacted Ti3AlC2–Cu composites produced by mechanical milling. Using X-ray and neutron diffraction techniques, it is demonstrated that the Cu mixing into the Al site is accompanied by lattice distortion, which leads to symmetry reduction from a hexagonal to a monoclinic structure. Such symmetry reduction likely results from this mixing through deviation of the A-site position from the special (0, 0, 1/4) position within the P63/mmc space group of the original Ti3AlC2 structure. Moreover, it is demonstrated that the Cu admixture into the A site can be adjusted from the composition of the reactant mixture. The lattice parameter variation of the solid solution compounds, with 10–50 atom % Cu in the A site, is found to be consistent with Vegard’s law." @default.
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- W2768215790 date "2017-11-15" @default.
- W2768215790 modified "2023-09-27" @default.
- W2768215790 title "Evidence for Symmetry Reduction in Ti<sub>3</sub>(Al<sub>1−δ</sub>Cu<sub>δ</sub>)C<sub>2</sub> MAX Phase Solid Solutions" @default.
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- W2768215790 doi "https://doi.org/10.1021/acs.inorgchem.7b01003" @default.
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