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- W2768223594 abstract "The general characteristics of the active center of the catalysts (including zinc-cobalt(III) double metal cyanide complex [Zn-Co(III) DMCC]) for the copolymerization reaction of carbon dioxide (CO2) with epoxide are summarized. By comparing the active center, catalytic performance of the Zn-Co(III) DMCC (and other catalysts) with HCAII enzyme in the organism for activating CO2 (COS and CS2), we proposed that the metal-hydroxide bond (M-OH), which is the real catalytic center of human carbonic anhydride II (HCAII), is also the catalytic (initiating) center for the copolymerization. It accelerates the copolymerization and forms a closed catalytic cycle through the chain transfer reaction to water (and thus strictly meets the definition of the catalyst). In addition, the metal-hydroxide bond catalysis could well explain the oxygen/sulfur exchange reaction (O/S ER) in metal (Zn, Cr)-catalyzed copolymerization of COS (and CS2) with epoxides. Therefore, it is very promising to learn from HCAII enzyme to develop biomimetic catalyst for highly active CO2/epoxide copolymerization in a well-controlled manner under mild conditions." @default.
- W2768223594 created "2017-12-04" @default.
- W2768223594 creator A5011812395 @default.
- W2768223594 creator A5044548260 @default.
- W2768223594 creator A5079171749 @default.
- W2768223594 creator A5083364328 @default.
- W2768223594 date "2017-11-21" @default.
- W2768223594 modified "2023-10-18" @default.
- W2768223594 title "HCAII-inspired catalysts for making carbon dioxide-based copolymers: The role of metal-hydroxide bond" @default.
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