Matches in SemOpenAlex for { <https://semopenalex.org/work/W2768466737> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2768466737 endingPage "426" @default.
- W2768466737 startingPage "419" @default.
- W2768466737 abstract "Abstract Co-KIT-6 mesoporous materials with Ia3d symmetry and Si/Co ratios of 50, 25, and 10 were prepared using hydrothermal one-pot synthesis. The Co-KIT-6 mesoporous materials were characterized by X-ray diffraction, N2 adsorption–desorption isotherms, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared, and X-ray photoelectron spectroscopy. The physicochemical characterization results show that all of the samples have well-ordered cubic mesostructures and that the structural integrity is preserved for nSi/nCo ratios as high as 10. It was found that most of the cobalt ions exist as isolated framework species, but for Co-KIT-6 with an nSi/nCo ratio of 10, the presence of extra-framework species/small cobalt oxide clusters cannot be excluded. The ability of these catalysts was tested by examining the conversion of the reaction of methylcyclopentane with hydrogen at atmospheric pressure and temperatures between 200 and 450 °C. The catalytic results show that their catalytic activity increases significantly with increasing cobalt content. The active sites, tetrahedrally coordinated Co and isolated atomic Co sites, were responsible for the endocyclic C C bond rupture between substituted secondary–tertiary carbon atoms, whereas the small clusters serve as active sites for the successive C C bond rupture. The ring-opening selectivity can be improved by increasing the density of isolated cobalt atom sites at low reaction temperatures." @default.
- W2768466737 created "2017-12-04" @default.
- W2768466737 creator A5001148591 @default.
- W2768466737 creator A5029019973 @default.
- W2768466737 creator A5033582109 @default.
- W2768466737 creator A5078882075 @default.
- W2768466737 date "2018-03-01" @default.
- W2768466737 modified "2023-10-18" @default.
- W2768466737 title "One-pot synthesis to engineer a Co-KIT-6 catalyst for the ring opening of methylcyclopentane" @default.
- W2768466737 cites W106514933 @default.
- W2768466737 cites W124482331 @default.
- W2768466737 cites W1963978007 @default.
- W2768466737 cites W1966553785 @default.
- W2768466737 cites W1966942394 @default.
- W2768466737 cites W1975287085 @default.
- W2768466737 cites W1981316657 @default.
- W2768466737 cites W1981364307 @default.
- W2768466737 cites W1981389968 @default.
- W2768466737 cites W1981562635 @default.
- W2768466737 cites W1985092468 @default.
- W2768466737 cites W1987891238 @default.
- W2768466737 cites W1994509291 @default.
- W2768466737 cites W2000049350 @default.
- W2768466737 cites W2002291340 @default.
- W2768466737 cites W2006475434 @default.
- W2768466737 cites W2013302593 @default.
- W2768466737 cites W2032537296 @default.
- W2768466737 cites W2048602037 @default.
- W2768466737 cites W2054859547 @default.
- W2768466737 cites W2056037149 @default.
- W2768466737 cites W2069912403 @default.
- W2768466737 cites W2075579677 @default.
- W2768466737 cites W2094256373 @default.
- W2768466737 cites W2100256773 @default.
- W2768466737 cites W2103285199 @default.
- W2768466737 cites W2119642033 @default.
- W2768466737 cites W2141002975 @default.
- W2768466737 cites W2230432632 @default.
- W2768466737 cites W2300081750 @default.
- W2768466737 cites W2334605959 @default.
- W2768466737 cites W2334978857 @default.
- W2768466737 cites W2885927010 @default.
- W2768466737 cites W2951972164 @default.
- W2768466737 doi "https://doi.org/10.1016/j.crci.2017.10.007" @default.
- W2768466737 hasPublicationYear "2018" @default.
- W2768466737 type Work @default.
- W2768466737 sameAs 2768466737 @default.
- W2768466737 citedByCount "1" @default.
- W2768466737 countsByYear W27684667372020 @default.
- W2768466737 crossrefType "journal-article" @default.
- W2768466737 hasAuthorship W2768466737A5001148591 @default.
- W2768466737 hasAuthorship W2768466737A5029019973 @default.
- W2768466737 hasAuthorship W2768466737A5033582109 @default.
- W2768466737 hasAuthorship W2768466737A5078882075 @default.
- W2768466737 hasBestOaLocation W27684667371 @default.
- W2768466737 hasConcept C161790260 @default.
- W2768466737 hasConcept C178790620 @default.
- W2768466737 hasConcept C185592680 @default.
- W2768466737 hasConcept C2776649630 @default.
- W2768466737 hasConcept C2780378348 @default.
- W2768466737 hasConcept C518104683 @default.
- W2768466737 hasConceptScore W2768466737C161790260 @default.
- W2768466737 hasConceptScore W2768466737C178790620 @default.
- W2768466737 hasConceptScore W2768466737C185592680 @default.
- W2768466737 hasConceptScore W2768466737C2776649630 @default.
- W2768466737 hasConceptScore W2768466737C2780378348 @default.
- W2768466737 hasConceptScore W2768466737C518104683 @default.
- W2768466737 hasIssue "3-4" @default.
- W2768466737 hasLocation W27684667371 @default.
- W2768466737 hasOpenAccess W2768466737 @default.
- W2768466737 hasPrimaryLocation W27684667371 @default.
- W2768466737 hasRelatedWork W2029118187 @default.
- W2768466737 hasRelatedWork W2039437863 @default.
- W2768466737 hasRelatedWork W2074930122 @default.
- W2768466737 hasRelatedWork W2076559997 @default.
- W2768466737 hasRelatedWork W2082852141 @default.
- W2768466737 hasRelatedWork W2119642033 @default.
- W2768466737 hasRelatedWork W2162041534 @default.
- W2768466737 hasRelatedWork W2343034960 @default.
- W2768466737 hasRelatedWork W2950387105 @default.
- W2768466737 hasRelatedWork W77516022 @default.
- W2768466737 hasVolume "21" @default.
- W2768466737 isParatext "false" @default.
- W2768466737 isRetracted "false" @default.
- W2768466737 magId "2768466737" @default.
- W2768466737 workType "article" @default.