FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2768494993> ?p ?o ?g. }

• W2768494993 endingPage "14670" @default.
• W2768494993 startingPage "14662" @default.
• W2768494993 abstract "The electronic structures of the diruthenium compounds Ru2(ap)4Cl (1, ap = 2-anilinopyridinate) and Ru2(ap)4OTf (2) were investigated with UV–vis, resonance Raman, and magnetic circular dichroism (MCD) spectroscopies; SQUID magnetometry; and density functional theory (DFT) calculations. Both compounds have quartet spin ground states with large axial zero-field splitting of ∼60 cm–1 that is characteristic of Ru25+ compounds having a (π*, δ*)3 electron configuration and a Ru–Ru bond order of ∼2.5. Two major visible absorption features are observed at ∼770 and 430 nm in the electronic spectra, the assignments of which have previously been ambiguous. Both bands have significant charge-transfer character with some contributions from d → d transitions. MCD spectra were measured to enable the identification of d → d transitions that are not easily observable by UV–vis spectroscopy. In this way, we are able to identify bands due to δ → δ* and δ → π* transitions at ∼16 100 and 11 200–12 300 cm–1, respectively, the latter band being sensitive to the π-donating character of the axial ligand. The Ru–Ru stretches are coupled with pyridine rocking motions and give rise to observed resonance Raman peaks at ∼350 and 420 cm–1, respectively." @default.
• W2768494993 created "2017-12-04" @default.
• W2768494993 creator A5038406479 @default.
• W2768494993 creator A5052342470 @default.
• W2768494993 creator A5052922381 @default.
• W2768494993 creator A5078013992 @default.
• W2768494993 creator A5078483518 @default.
• W2768494993 creator A5084896370 @default.
• W2768494993 date "2017-11-15" @default.
• W2768494993 modified "2023-09-26" @default.
• W2768494993 title "Electronic Structure of Anilinopyridinate-Supported Ru₂⁵⁺ Paddlewheel Compounds" @default.
• W2768494993 cites W1514523329 @default.
• W2768494993 cites W156237410 @default.
• W2768494993 cites W1965058772 @default.
• W2768494993 cites W1977199622 @default.
• W2768494993 cites W1979018376 @default.
• W2768494993 cites W1982356449 @default.
• W2768494993 cites W1985459995 @default.
• W2768494993 cites W1988091937 @default.
• W2768494993 cites W1994847204 @default.
• W2768494993 cites W1996370883 @default.
• W2768494993 cites W1997362453 @default.
• W2768494993 cites W1998613997 @default.
• W2768494993 cites W2000862731 @default.
• W2768494993 cites W2002147211 @default.
• W2768494993 cites W2002281689 @default.
• W2768494993 cites W2010198469 @default.
• W2768494993 cites W2010805816 @default.
• W2768494993 cites W2012866556 @default.
• W2768494993 cites W2013404865 @default.
• W2768494993 cites W2013856569 @default.
• W2768494993 cites W2014855009 @default.
• W2768494993 cites W2016052942 @default.
• W2768494993 cites W2016346225 @default.
• W2768494993 cites W2016800344 @default.
• W2768494993 cites W2019481980 @default.
• W2768494993 cites W2023271753 @default.
• W2768494993 cites W2024887669 @default.
• W2768494993 cites W2025732472 @default.
• W2768494993 cites W2028046413 @default.
• W2768494993 cites W2028690686 @default.
• W2768494993 cites W2030687437 @default.
• W2768494993 cites W2033928452 @default.
• W2768494993 cites W2035603229 @default.
• W2768494993 cites W2038533471 @default.
• W2768494993 cites W2041700407 @default.
• W2768494993 cites W2041859473 @default.
• W2768494993 cites W2045236580 @default.
• W2768494993 cites W2050426971 @default.
• W2768494993 cites W2051173396 @default.
• W2768494993 cites W2053391735 @default.
• W2768494993 cites W2055563809 @default.
• W2768494993 cites W2059833072 @default.
• W2768494993 cites W2060175615 @default.
• W2768494993 cites W2067718414 @default.
• W2768494993 cites W2070226417 @default.
• W2768494993 cites W2076442433 @default.
• W2768494993 cites W2078146328 @default.
• W2768494993 cites W2079198022 @default.
• W2768494993 cites W2082955660 @default.
• W2768494993 cites W2083976921 @default.
• W2768494993 cites W2086957099 @default.
• W2768494993 cites W2090665363 @default.
• W2768494993 cites W2093792620 @default.
• W2768494993 cites W2105564187 @default.
• W2768494993 cites W2114502801 @default.
• W2768494993 cites W2117867509 @default.
• W2768494993 cites W2132629607 @default.
• W2768494993 cites W2148284063 @default.
• W2768494993 cites W2148928471 @default.
• W2768494993 cites W2156843860 @default.
• W2768494993 cites W2166036314 @default.
• W2768494993 cites W2222547697 @default.
• W2768494993 cites W2317598425 @default.
• W2768494993 cites W2318411184 @default.
• W2768494993 cites W2321547008 @default.
• W2768494993 cites W2328529894 @default.
• W2768494993 cites W2334343303 @default.
• W2768494993 cites W2413779110 @default.
• W2768494993 cites W2413888649 @default.
• W2768494993 cites W2464840223 @default.
• W2768494993 cites W2466165092 @default.
• W2768494993 cites W2492807587 @default.
• W2768494993 cites W2509467280 @default.
• W2768494993 cites W2566597733 @default.
• W2768494993 cites W2610042830 @default.
• W2768494993 cites W2950574485 @default.
• W2768494993 cites W2950797595 @default.
• W2768494993 cites W2951610854 @default.
• W2768494993 cites W2951727904 @default.
• W2768494993 cites W2952397995 @default.
• W2768494993 cites W3138050252 @default.
• W2768494993 cites W4238005405 @default.
• W2768494993 doi "https://doi.org/10.1021/acs.inorgchem.7b02557" @default.
• W2768494993 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29140085" @default.
• W2768494993 hasPublicationYear "2017" @default.
• W2768494993 type Work @default.
• W2768494993 sameAs 2768494993 @default.

• next