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- W2768820148 abstract "AbstractTwo copper(II) complexes with the general formula [Cu(L)(H2O)](ClO4)2 (1) and [Cu(L)2](ClO4)2 (2), where L=3-((pyridin-2-ylmethyl)amino)propanamide, were synthesized and characterized by elemental analyses, IR, UV–vis spectroscopy techniques and molar conductance measurements. The crystal structures of the complexes were identified by single crystal X-ray diffraction analysis. The tridentate ligand L acts as an N2O-donor through the nitrogen atoms of the pyridine and amine moieties as well the oxygen atom of the amide group. The copper(II) ions in both complexes have distorted octahedron structures so that the Cu(II) ion in 1 is coordinated by an aqua ligand and a tridentate ligand defining the basal plane, and by two oxygen atoms of the perchlorate ions occupying the axial positions. However, two ligands L are coordinated to the copper(II) ion in 2, where four nitrogen atoms of pyridine and amine groups occupy the equatorial positions and two oxygen atoms of the amide moieties exist in the apices..." @default.
- W2768820148 created "2017-12-04" @default.
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- W2768820148 date "2017-11-02" @default.
- W2768820148 modified "2023-10-17" @default.
- W2768820148 title "Copper(II) complexes containing hemilabile tridentate ligand as chromotropic probes" @default.
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- W2768820148 doi "https://doi.org/10.1080/00958972.2017.1404996" @default.
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