FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2768915906> ?p ?o ?g. }

• W2768915906 endingPage "9274" @default.
• W2768915906 startingPage "9262" @default.
• W2768915906 abstract "The yield of vibrationally excited OH fragments resulting from the vibrationally mediated photodissociation of methyl hydroperoxide (CH3OOH) excited in the vicinity of its 2νOH and 3νOH stretching overtones is compared with that resulting from excitation of the molecule to states with three quanta in the CH stretches and to the state with two quanta in the OH stretch and one in the OOH bend (2νOH + νOOH). We find that the OH fragment vibrational state distribution depends strongly on the vibrational state of CH3OOH prior to photodissociation. Specifically, dissociation from the CH stretch overtones and the stretch/bend combination band involving the OH stretch and OOH bend produced significantly less vibrationally excited OH fragments compared to that produced following excitation of CH3OOH to an overtone in the OH stretch. While the absence of vibrationally excited OH photoproducts following excitation of the CH overtone is not surprising, the lack of vibrationally excited OH following excitation to the 2νOH+νOOH combination band is unexpected given that photodissociation following excitation to the lower-energy 2νOH state produces OH products in v = 1 as well as in its ground state. This trend persists even when the electronic photodissociation wavelength is changed from 532 to 355 nm and thus suggests that the observed disparity arises from differences in the nature of the initially populated vibrational states. This lack of vibrationally excited OH products likely reflects the enhanced intramolecular vibrational energy redistribution associated with the stretch/bend combination level compared to the pure OH stretch overtone. Consistent with this hypothesis, photodissociation from the stretch/bend combination level of the smaller HOOH molecule produces more vibrationally excited OH fragments compared to that resulting from the corresponding state of CH3OOH. These results are investigated using second-order vibrational perturbation theory based on an internal coordinate representation of the normal modes. Consistent with the observations, the first-order correction to the wave function shows stronger coupling of the 2νOH+νOOH state to states with torsion excitation compared to the other bands considered in this study." @default.
• W2768915906 created "2017-12-04" @default.
• W2768915906 creator A5013352378 @default.
• W2768915906 creator A5046613137 @default.
• W2768915906 creator A5083027997 @default.
• W2768915906 creator A5087222657 @default.
• W2768915906 date "2017-11-27" @default.
• W2768915906 modified "2023-10-17" @default.
• W2768915906 title "Role of Torsion-Vibration Coupling in the Overtone Spectrum and Vibrationally Mediated Photochemistry of CH₃OOH and HOOH" @default.
• W2768915906 cites W1963676758 @default.
• W2768915906 cites W1966536010 @default.
• W2768915906 cites W1966829843 @default.
• W2768915906 cites W1970677759 @default.
• W2768915906 cites W1987399251 @default.
• W2768915906 cites W1990532010 @default.
• W2768915906 cites W1992863078 @default.
• W2768915906 cites W2003579465 @default.
• W2768915906 cites W2006869700 @default.
• W2768915906 cites W2008391081 @default.
• W2768915906 cites W2010022485 @default.
• W2768915906 cites W2020553218 @default.
• W2768915906 cites W2020844195 @default.
• W2768915906 cites W2021738929 @default.
• W2768915906 cites W2025017695 @default.
• W2768915906 cites W2026213782 @default.
• W2768915906 cites W2027822530 @default.
• W2768915906 cites W2034778956 @default.
• W2768915906 cites W2035706953 @default.
• W2768915906 cites W2041335884 @default.
• W2768915906 cites W2043647160 @default.
• W2768915906 cites W2057480845 @default.
• W2768915906 cites W2057785791 @default.
• W2768915906 cites W2064540560 @default.
• W2768915906 cites W2067315129 @default.
• W2768915906 cites W2067514978 @default.
• W2768915906 cites W2077929747 @default.
• W2768915906 cites W2082899773 @default.
• W2768915906 cites W2089628839 @default.
• W2768915906 cites W2091914131 @default.
• W2768915906 cites W2094490979 @default.
• W2768915906 cites W2111871026 @default.
• W2768915906 cites W2114106656 @default.
• W2768915906 cites W2114609466 @default.
• W2768915906 cites W2160665666 @default.
• W2768915906 cites W2175654402 @default.
• W2768915906 cites W2252798740 @default.
• W2768915906 cites W2280820562 @default.
• W2768915906 cites W2318824894 @default.
• W2768915906 cites W2338291861 @default.
• W2768915906 cites W2566987699 @default.
• W2768915906 cites W2949184353 @default.
• W2768915906 doi "https://doi.org/10.1021/acs.jpca.7b09778" @default.
• W2768915906 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29172536" @default.
• W2768915906 hasPublicationYear "2017" @default.
• W2768915906 type Work @default.
• W2768915906 sameAs 2768915906 @default.
• W2768915906 citedByCount "10" @default.
• W2768915906 countsByYear W27689159062018 @default.
• W2768915906 countsByYear W27689159062019 @default.
• W2768915906 countsByYear W27689159062020 @default.
• W2768915906 countsByYear W27689159062021 @default.
• W2768915906 countsByYear W27689159062022 @default.
• W2768915906 countsByYear W27689159062023 @default.
• W2768915906 crossrefType "journal-article" @default.
• W2768915906 hasAuthorship W2768915906A5013352378 @default.
• W2768915906 hasAuthorship W2768915906A5046613137 @default.
• W2768915906 hasAuthorship W2768915906A5083027997 @default.
• W2768915906 hasAuthorship W2768915906A5087222657 @default.
• W2768915906 hasConcept C102931765 @default.
• W2768915906 hasConcept C121332964 @default.
• W2768915906 hasConcept C1276947 @default.
• W2768915906 hasConcept C147789679 @default.
• W2768915906 hasConcept C181500209 @default.
• W2768915906 hasConcept C184779094 @default.
• W2768915906 hasConcept C185592680 @default.
• W2768915906 hasConcept C192468462 @default.
• W2768915906 hasConcept C38615331 @default.
• W2768915906 hasConcept C4839761 @default.
• W2768915906 hasConcept C54582936 @default.
• W2768915906 hasConcept C62520636 @default.
• W2768915906 hasConcept C69523127 @default.
• W2768915906 hasConcept C75473681 @default.
• W2768915906 hasConcept C83581075 @default.
• W2768915906 hasConceptScore W2768915906C102931765 @default.
• W2768915906 hasConceptScore W2768915906C121332964 @default.
• W2768915906 hasConceptScore W2768915906C1276947 @default.
• W2768915906 hasConceptScore W2768915906C147789679 @default.
• W2768915906 hasConceptScore W2768915906C181500209 @default.
• W2768915906 hasConceptScore W2768915906C184779094 @default.
• W2768915906 hasConceptScore W2768915906C185592680 @default.
• W2768915906 hasConceptScore W2768915906C192468462 @default.
• W2768915906 hasConceptScore W2768915906C38615331 @default.
• W2768915906 hasConceptScore W2768915906C4839761 @default.
• W2768915906 hasConceptScore W2768915906C54582936 @default.
• W2768915906 hasConceptScore W2768915906C62520636 @default.
• W2768915906 hasConceptScore W2768915906C69523127 @default.
• W2768915906 hasConceptScore W2768915906C75473681 @default.
• W2768915906 hasConceptScore W2768915906C83581075 @default.

• next