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• W2768940250 abstract "A new rhodamine-based chemosensor 1 with a six-membered spirocyclic ring has been synthesized, which exhibits excellent pH stability and shows selective “turn-on” fluorescent detection of Cu2+ ions over a series of other metal ions including Cu+ ions. The expansion of spirocycle improves the stability and selectivity of the chemosensors in sensing of metal ions. Till today only few rhodamine structures R1–R5 with thiourea-, hydrazine amide-, or pyrrole-decorated six-membered spirocyclic rings are known that exhibit metal-ion sensing via C–N bond cleavage of the spiro ring. In this context, rhodamine compound that responds to the metal ion through C–C bond cleavage of the six-membered spiro ring is completely unknown. The present example is a first-time report that demonstrates selective sensing of Cu2+ ions through C–C bond cleavage over the conventional existing systems in the literature. The chemosensor 1 is cell permeable and can detect Cu2+ in live cells using confocal microscopy in the biologically relevant pH range with high photostability." @default.
• W2768940250 created "2017-12-04" @default.
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• W2768940250 date "2017-11-20" @default.
• W2768940250 modified "2023-10-11" @default.
• W2768940250 title "New Six-Membered pH-Insensitive Rhodamine Spirocycle in Selective Sensing of Cu²⁺ through C–C Bond Cleavage and Its Application in Cell Imaging" @default.
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• W2768940250 doi "https://doi.org/10.1021/acsomega.7b01324" @default.
• W2768940250 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6045328" @default.
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