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- W2769127735 abstract "Abstract An extended π‐system containing two [3]cumulene fragments separated by a p‐carboquinoid and stabilized by two capping N‐heterocyclic carbenes (NHCs) has been prepared. Mono‐ and bis(imidazolidinium ethynyl) cations have also been synthesized from the reaction of an NHC with phenylethynyl bromide or 1,4‐bis(bromoethynyl)benzene. Cyclic voltammetry coupled with synthetic and structural studies showed that the dication is readily reduced to a neutral, singlet bis‐1,4‐([3]cumulene)‐p‐carboquinoid as a result of the π‐accepting properties of the capping NHCs." @default.
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- W2769127735 date "2017-12-14" @default.
- W2769127735 modified "2023-10-17" @default.
- W2769127735 title "Mono‐ and Bis(imidazolidinium ethynyl) Cations and Reduction of the Latter To Give an Extended Bis‐1,4‐([3]Cumulene)‐<i>p</i>‐carboquinoid System" @default.
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- W2769127735 doi "https://doi.org/10.1002/anie.201711031" @default.
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