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- W2769162309 abstract "In this work lipase CaLB was immobilized on functionalized Pd-SiO2 nanoparticles in order to simplify the DKR of α-methylbenzylamine. Hybrid biocatalysts showed immobilization efficiencies of 82%, 80% and 76% when containing 1, 5 and 10% of Pd respectively. On DKR reaction values of ee > 99% and conversion of 82% were found with only 1% of Pd, generating a productivity of 2.21 mg of product h−1 mg of support−1 against 0.76 found by N435®. Compared to commercial N435®, the novel biocatalysts showed protein loads about 15-fold lower and higher activity, demonstrating competitive performances and high industrial applications." @default.
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- W2769162309 date "2017-12-01" @default.
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- W2769162309 title "New Biosilified Pd-lipase hybrid biocatalysts for dynamic resolution of amines" @default.
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- W2769162309 doi "https://doi.org/10.1016/j.tetlet.2017.11.031" @default.
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