Matches in SemOpenAlex for { <https://semopenalex.org/work/W2769277367> ?p ?o ?g. }
- W2769277367 endingPage "6637" @default.
- W2769277367 startingPage "6634" @default.
- W2769277367 abstract "The C(1)–C(13) fragment of the antimitotic marine macrolide leiodermatolide is prepared in seven steps via hydrogenative and transfer-hydrogenative reductive C–C couplings. A hydrogen-mediated reductive coupling of acetylene with a Roche-type aldehyde is used to construct C(7)–C(13). A 2-propanol-mediated reductive coupling of allyl acetate with (E)-2-methylbut-2-enal at a low loading of iridium (1 mol %) is used to construct C(1)–C(6), which is converted to an allylsilane using Oestereich’s copper-catalyzed allylic substitution of Si–Zn reagents. The union of the C(1)–C(6) and C(7)–C(13) fragments is achieved via stereoselective Sakurai allylation." @default.
- W2769277367 created "2017-12-04" @default.
- W2769277367 creator A5022359349 @default.
- W2769277367 creator A5042928999 @default.
- W2769277367 creator A5047469781 @default.
- W2769277367 creator A5063266925 @default.
- W2769277367 date "2017-11-23" @default.
- W2769277367 modified "2023-09-28" @default.
- W2769277367 title "Synthesis of the C(1)–C(13) Fragment of Leiodermatolide via Hydrogen-Mediated C–C Bond Formation" @default.
- W2769277367 cites W1860598299 @default.
- W2769277367 cites W1970436622 @default.
- W2769277367 cites W1971579914 @default.
- W2769277367 cites W1972456842 @default.
- W2769277367 cites W1979133614 @default.
- W2769277367 cites W1988850101 @default.
- W2769277367 cites W1994031176 @default.
- W2769277367 cites W2008312946 @default.
- W2769277367 cites W2010767982 @default.
- W2769277367 cites W2019123141 @default.
- W2769277367 cites W2023773137 @default.
- W2769277367 cites W2027401817 @default.
- W2769277367 cites W2039234500 @default.
- W2769277367 cites W2039386701 @default.
- W2769277367 cites W2040443096 @default.
- W2769277367 cites W2045002801 @default.
- W2769277367 cites W2046544372 @default.
- W2769277367 cites W2051609133 @default.
- W2769277367 cites W2063812016 @default.
- W2769277367 cites W2065127160 @default.
- W2769277367 cites W2077713582 @default.
- W2769277367 cites W2083456617 @default.
- W2769277367 cites W2086684339 @default.
- W2769277367 cites W2091720709 @default.
- W2769277367 cites W2092658289 @default.
- W2769277367 cites W2093855538 @default.
- W2769277367 cites W2094923566 @default.
- W2769277367 cites W2095950885 @default.
- W2769277367 cites W2101166252 @default.
- W2769277367 cites W2106718031 @default.
- W2769277367 cites W2111868723 @default.
- W2769277367 cites W2117508977 @default.
- W2769277367 cites W2121535692 @default.
- W2769277367 cites W2144040368 @default.
- W2769277367 cites W2150531110 @default.
- W2769277367 cites W2168810478 @default.
- W2769277367 cites W2170912242 @default.
- W2769277367 cites W2313908369 @default.
- W2769277367 cites W2315478834 @default.
- W2769277367 cites W2343167667 @default.
- W2769277367 cites W2416238165 @default.
- W2769277367 cites W2466938594 @default.
- W2769277367 cites W2538325260 @default.
- W2769277367 cites W2555334739 @default.
- W2769277367 cites W2581813867 @default.
- W2769277367 cites W2744506385 @default.
- W2769277367 cites W4237536125 @default.
- W2769277367 cites W905101748 @default.
- W2769277367 doi "https://doi.org/10.1021/acs.orglett.7b03351" @default.
- W2769277367 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5732063" @default.
- W2769277367 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29168383" @default.
- W2769277367 hasPublicationYear "2017" @default.
- W2769277367 type Work @default.
- W2769277367 sameAs 2769277367 @default.
- W2769277367 citedByCount "6" @default.
- W2769277367 countsByYear W27692773672018 @default.
- W2769277367 countsByYear W27692773672019 @default.
- W2769277367 countsByYear W27692773672021 @default.
- W2769277367 countsByYear W27692773672022 @default.
- W2769277367 countsByYear W27692773672023 @default.
- W2769277367 crossrefType "journal-article" @default.
- W2769277367 hasAuthorship W2769277367A5022359349 @default.
- W2769277367 hasAuthorship W2769277367A5042928999 @default.
- W2769277367 hasAuthorship W2769277367A5047469781 @default.
- W2769277367 hasAuthorship W2769277367A5063266925 @default.
- W2769277367 hasBestOaLocation W27692773671 @default.
- W2769277367 hasConcept C120095180 @default.
- W2769277367 hasConcept C155647269 @default.
- W2769277367 hasConcept C161790260 @default.
- W2769277367 hasConcept C178790620 @default.
- W2769277367 hasConcept C181647583 @default.
- W2769277367 hasConcept C185592680 @default.
- W2769277367 hasConcept C2777517455 @default.
- W2769277367 hasConcept C2777961443 @default.
- W2769277367 hasConcept C2779825165 @default.
- W2769277367 hasConcept C512968161 @default.
- W2769277367 hasConcept C528581852 @default.
- W2769277367 hasConcept C71240020 @default.
- W2769277367 hasConceptScore W2769277367C120095180 @default.
- W2769277367 hasConceptScore W2769277367C155647269 @default.
- W2769277367 hasConceptScore W2769277367C161790260 @default.
- W2769277367 hasConceptScore W2769277367C178790620 @default.
- W2769277367 hasConceptScore W2769277367C181647583 @default.
- W2769277367 hasConceptScore W2769277367C185592680 @default.
- W2769277367 hasConceptScore W2769277367C2777517455 @default.
- W2769277367 hasConceptScore W2769277367C2777961443 @default.
- W2769277367 hasConceptScore W2769277367C2779825165 @default.
- W2769277367 hasConceptScore W2769277367C512968161 @default.
- W2769277367 hasConceptScore W2769277367C528581852 @default.