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• W2769348093 abstract "Abstract A palladium‐catalyzed cascade reaction has been realized for the synthesis of 5 H ‐pyrrolo[2,3‐ b ]pyrazines and 5 H ‐pyrazino[2,3‐ b ]indoles from benzyl isocyanide by choosing o ‐pivaloyloximes or o ‐iodoanilines as a suitable substrate. The key steps involved are (i) oxidative addition of palladium through N–O or C–I cleavage; (ii) migratory double isocyanide insertion; and (iii) cross‐dehydrogenative coupling. Notable features are good functional group tolerance as well as formation of three C–C and one C–N bonds. magnified image" @default.
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• W2769348093 date "2018-01-19" @default.
• W2769348093 modified "2023-10-02" @default.
• W2769348093 title "Synthesis of Fused-Pyrazines <i>via</i> Palladium-Catalyzed Double Benzyl Isocyanide Insertion and Cross-Dehydrogenative Coupling" @default.
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• W2769348093 doi "https://doi.org/10.1002/adsc.201701202" @default.
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