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• W2769737949 abstract "A number of cyclic dienes containing the allylsilane moiety were prepared by a Birch reduction and subjected to iridium-catalyzed regioselective and asymmetric hydrogenation, which provided chiral allylsilanes in high conversion and enantiomeric excess (up to 99 % ee). The compounds were successively used in the Hosomi-Sakurai allylation with various aldehydes employing TiCl4 as Lewis acid, providing adducts with two additional stereogenic centers in excellent diastereoselectivity." @default.
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• W2769737949 date "2018-01-02" @default.
• W2769737949 modified "2023-10-16" @default.
• W2769737949 title "Ir-Catalyzed Asymmetric and Regioselective Hydrogenation of Cyclic Allylsilanes and Generation of Quaternary Stereocenters via the Hosomi-Sakurai Allylation" @default.
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• W2769737949 doi "https://doi.org/10.1002/chem.201704684" @default.
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