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- W2769769063 endingPage "5012" @default.
- W2769769063 startingPage "5003" @default.
- W2769769063 abstract "The open, noninteracting vicinal P/B frustrated Lewis pair (FLP) at the very rigid, dibenzobicyclo[2.2.2]octadiene (“semi-triptycene”) framework shows a trans 1,2-arrangement of the Mes2P– and (C6F5)2B– Lewis base/Lewis acid pair. It is an active dihydrogen splitting reagent and shows a great variety of typical frustrated Lewis pair reactions under mild reaction conditions. This includes the 1,1-addition reaction to nitric oxide (NO) to form a persistent FLPNO• nitroxide radical as well as CO reduction by Piers’ borane [HB(C6F5)2] at the reactive FLP template. The new FLP undergoes thermodynamically favorable 1,4-addition reactions to 1,2-diketones. Most products were characterized by X-ray diffraction, and the 1,4-diketone addition reaction was analyzed by DFT calculation. A comparison with the internally interacting “parent” vicinal Mes2PCH2CH2B(C6F5)2 system revealed some decisive indications for very active FLPs." @default.
- W2769769063 created "2017-12-04" @default.
- W2769769063 creator A5010252691 @default.
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- W2769769063 creator A5034807035 @default.
- W2769769063 creator A5048542589 @default.
- W2769769063 creator A5081426782 @default.
- W2769769063 date "2017-11-28" @default.
- W2769769063 modified "2023-10-18" @default.
- W2769769063 title "Frustrated Lewis Pair Behavior of an Open, Noninteracting Phosphane/Borane Pair at a Rigid Organic Framework: Exploring Decisive Factors for FLP Activity" @default.
- W2769769063 cites W118062614 @default.
- W2769769063 cites W1501319738 @default.
- W2769769063 cites W1524847915 @default.
- W2769769063 cites W1897198241 @default.
- W2769769063 cites W1964740687 @default.
- W2769769063 cites W1976609113 @default.
- W2769769063 cites W1977225494 @default.
- W2769769063 cites W1981176215 @default.
- W2769769063 cites W1985635200 @default.
- W2769769063 cites W1987875123 @default.
- W2769769063 cites W1988091937 @default.
- W2769769063 cites W1990422042 @default.
- W2769769063 cites W1991489201 @default.
- W2769769063 cites W1993158111 @default.
- W2769769063 cites W1994567008 @default.
- W2769769063 cites W1998638277 @default.
- W2769769063 cites W1998832785 @default.
- W2769769063 cites W2001670536 @default.
- W2769769063 cites W2002482043 @default.
- W2769769063 cites W2003286577 @default.
- W2769769063 cites W2011329180 @default.
- W2769769063 cites W2013668323 @default.
- W2769769063 cites W2015350467 @default.
- W2769769063 cites W2018382784 @default.
- W2769769063 cites W2024177283 @default.
- W2769769063 cites W2030894031 @default.
- W2769769063 cites W2031602641 @default.
- W2769769063 cites W2037935642 @default.
- W2769769063 cites W2043252767 @default.
- W2769769063 cites W2045413575 @default.
- W2769769063 cites W2046141105 @default.
- W2769769063 cites W2046199419 @default.
- W2769769063 cites W2050950038 @default.
- W2769769063 cites W2053157033 @default.
- W2769769063 cites W2053182396 @default.
- W2769769063 cites W2056266749 @default.
- W2769769063 cites W2061936071 @default.
- W2769769063 cites W2063049222 @default.
- W2769769063 cites W2066170483 @default.
- W2769769063 cites W2070721394 @default.
- W2769769063 cites W2075434209 @default.
- W2769769063 cites W2075903690 @default.
- W2769769063 cites W2076878961 @default.
- W2769769063 cites W2076934102 @default.
- W2769769063 cites W2078078100 @default.
- W2769769063 cites W2087564639 @default.
- W2769769063 cites W2092157292 @default.
- W2769769063 cites W2093658051 @default.
- W2769769063 cites W2096747776 @default.
- W2769769063 cites W2098036485 @default.
- W2769769063 cites W2103304695 @default.
- W2769769063 cites W2106203610 @default.
- W2769769063 cites W2106634665 @default.
- W2769769063 cites W2107525189 @default.
- W2769769063 cites W2119547517 @default.
- W2769769063 cites W2119590660 @default.
- W2769769063 cites W2131565822 @default.
- W2769769063 cites W2132940943 @default.
- W2769769063 cites W2136849497 @default.
- W2769769063 cites W2140556195 @default.
- W2769769063 cites W2143453620 @default.
- W2769769063 cites W2147741946 @default.
- W2769769063 cites W2152740524 @default.
- W2769769063 cites W2169858698 @default.
- W2769769063 cites W2171180989 @default.
- W2769769063 cites W2171515789 @default.
- W2769769063 cites W2172124378 @default.
- W2769769063 cites W2233219937 @default.
- W2769769063 cites W2306581482 @default.
- W2769769063 cites W2309618881 @default.
- W2769769063 cites W2311333118 @default.
- W2769769063 cites W2312931908 @default.
- W2769769063 cites W2312934384 @default.
- W2769769063 cites W2313302198 @default.
- W2769769063 cites W2315988044 @default.
- W2769769063 cites W2322304460 @default.
- W2769769063 cites W2323431342 @default.
- W2769769063 cites W2324586646 @default.
- W2769769063 cites W2324621744 @default.
- W2769769063 cites W2327421018 @default.
- W2769769063 cites W2329177969 @default.
- W2769769063 cites W2329880981 @default.
- W2769769063 cites W2343009667 @default.
- W2769769063 cites W2464148424 @default.
- W2769769063 cites W2467393990 @default.
- W2769769063 cites W2560096417 @default.
- W2769769063 cites W2560660394 @default.
- W2769769063 cites W2605949361 @default.