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- W2769941402 abstract "Abstract New hetero-stilbene derivatives, namely cis/trans-2/3/4-(2-vinylstyryl)pyridines, have been synthesized by Wittig reaction from the diphosphonium salt of α,α′-o-xylenedibromide, formaldehyde and 2/3/4-pyridinecarbaldehydes. The 2/3/4-(2-vinylstyryl)pyridines afforded, by photochemical intramolecular cycloaddition and cyclization reactions, diverse new polycyclic products with the pyridine ring integrated into the polycyclic skeletons. All of the new benzobicyclo[3.2.1]octadiene, benzobicyclo[2.1.1]hexene and vinyl-benzoquinoline products were identified and characterized by spectroscopic methods. Isomerized dihydro-intermediates (DHQs), that formed as a result of [1,n-H] shifts were also isolated, identified and characterized. DHQ intermediate isomers were never isolated in these conditions before." @default.
- W2769941402 created "2017-12-04" @default.
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- W2769941402 date "2018-03-01" @default.
- W2769941402 modified "2023-09-27" @default.
- W2769941402 title "Excited state reactions of β -pyridyl- o -divinylbenzenes as a pathway to versatile polycyclic compounds with the unusual entrapment of multiple isomerized dihydro-intermediates" @default.
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- W2769941402 doi "https://doi.org/10.1016/j.molstruc.2017.11.100" @default.
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