Matches in SemOpenAlex for { <https://semopenalex.org/work/W2769951627> ?p ?o ?g. }
- W2769951627 endingPage "294" @default.
- W2769951627 startingPage "287" @default.
- W2769951627 abstract "Nanozirconia supported ruthenium(0) nanoparticles (Ru0/ZrO2) were prepared by impregnation of ruthenium(III) cations on the surface of zirconia followed by their reduction with sodium borohydride at room temperature. Ru0/ZrO2 was isolated from the reaction solution by centrifugation and characterized by ICP-OES, XRD, TEM, SEM−EDS and XPS techniques. All the results reveal that ruthenium(0) nanoparticles were successfully supported on zirconia and the resulting Ru0/ZrO2 is a highly active and reusable catalyst for hydrogen generation from the hydrolysis of ammonia borane with a turnover frequency value of 173 min−1 at 25 °C. The reusability and catalytic lifetime tests reveal that Ru0/ZrO2 is still active in the subsequent runs of hydrolysis of ammonia borane preserving 67% of the initial catalytic activity even after the fifth run and Ru0/ZrO2 provides 72,500 turnovers (mol H2/mol Ru) before deactivation at 25 °C. Our report also includes the results of kinetic studies depending on the catalyst concentration and temperature to determine the activation energy (Ea = 58 ± 2 kJ/mol) for hydrolytic dehydrogenation of AB." @default.
- W2769951627 created "2017-12-04" @default.
- W2769951627 creator A5039448841 @default.
- W2769951627 creator A5040800804 @default.
- W2769951627 date "2018-03-01" @default.
- W2769951627 modified "2023-10-16" @default.
- W2769951627 title "Nanozirconia supported ruthenium(0) nanoparticles: Highly active and reusable catalyst in hydrolytic dehydrogenation of ammonia borane" @default.
- W2769951627 cites W1968561644 @default.
- W2769951627 cites W1983897009 @default.
- W2769951627 cites W1985222907 @default.
- W2769951627 cites W1996161136 @default.
- W2769951627 cites W1996871018 @default.
- W2769951627 cites W1997612576 @default.
- W2769951627 cites W2001151038 @default.
- W2769951627 cites W2002811048 @default.
- W2769951627 cites W2009794593 @default.
- W2769951627 cites W2025194298 @default.
- W2769951627 cites W2027906166 @default.
- W2769951627 cites W2031162468 @default.
- W2769951627 cites W2039293576 @default.
- W2769951627 cites W2052843071 @default.
- W2769951627 cites W2062930697 @default.
- W2769951627 cites W2069819011 @default.
- W2769951627 cites W2072189459 @default.
- W2769951627 cites W2073443209 @default.
- W2769951627 cites W2089627608 @default.
- W2769951627 cites W2092006330 @default.
- W2769951627 cites W2144488373 @default.
- W2769951627 cites W2153921207 @default.
- W2769951627 cites W2167383445 @default.
- W2769951627 cites W2175283922 @default.
- W2769951627 cites W2192792723 @default.
- W2769951627 cites W2233184588 @default.
- W2769951627 cites W2305175741 @default.
- W2769951627 cites W2327481123 @default.
- W2769951627 cites W2329484432 @default.
- W2769951627 cites W2338755954 @default.
- W2769951627 cites W2344664381 @default.
- W2769951627 cites W2398758152 @default.
- W2769951627 cites W2411936162 @default.
- W2769951627 cites W2414894137 @default.
- W2769951627 cites W2415840416 @default.
- W2769951627 cites W2567684166 @default.
- W2769951627 cites W2591601898 @default.
- W2769951627 cites W2599276284 @default.
- W2769951627 cites W2612765542 @default.
- W2769951627 cites W2617803412 @default.
- W2769951627 cites W2621019167 @default.
- W2769951627 doi "https://doi.org/10.1016/j.jcis.2017.11.037" @default.
- W2769951627 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29156236" @default.
- W2769951627 hasPublicationYear "2018" @default.
- W2769951627 type Work @default.
- W2769951627 sameAs 2769951627 @default.
- W2769951627 citedByCount "54" @default.
- W2769951627 countsByYear W27699516272018 @default.
- W2769951627 countsByYear W27699516272019 @default.
- W2769951627 countsByYear W27699516272020 @default.
- W2769951627 countsByYear W27699516272021 @default.
- W2769951627 countsByYear W27699516272022 @default.
- W2769951627 countsByYear W27699516272023 @default.
- W2769951627 crossrefType "journal-article" @default.
- W2769951627 hasAuthorship W2769951627A5039448841 @default.
- W2769951627 hasAuthorship W2769951627A5040800804 @default.
- W2769951627 hasConcept C119889771 @default.
- W2769951627 hasConcept C13965031 @default.
- W2769951627 hasConcept C155672457 @default.
- W2769951627 hasConcept C161790260 @default.
- W2769951627 hasConcept C171250308 @default.
- W2769951627 hasConcept C178790620 @default.
- W2769951627 hasConcept C179104552 @default.
- W2769951627 hasConcept C185592680 @default.
- W2769951627 hasConcept C192562407 @default.
- W2769951627 hasConcept C2778470625 @default.
- W2769951627 hasConcept C2778826510 @default.
- W2769951627 hasConcept C2780048404 @default.
- W2769951627 hasConcept C555196967 @default.
- W2769951627 hasConcept C94412978 @default.
- W2769951627 hasConceptScore W2769951627C119889771 @default.
- W2769951627 hasConceptScore W2769951627C13965031 @default.
- W2769951627 hasConceptScore W2769951627C155672457 @default.
- W2769951627 hasConceptScore W2769951627C161790260 @default.
- W2769951627 hasConceptScore W2769951627C171250308 @default.
- W2769951627 hasConceptScore W2769951627C178790620 @default.
- W2769951627 hasConceptScore W2769951627C179104552 @default.
- W2769951627 hasConceptScore W2769951627C185592680 @default.
- W2769951627 hasConceptScore W2769951627C192562407 @default.
- W2769951627 hasConceptScore W2769951627C2778470625 @default.
- W2769951627 hasConceptScore W2769951627C2778826510 @default.
- W2769951627 hasConceptScore W2769951627C2780048404 @default.
- W2769951627 hasConceptScore W2769951627C555196967 @default.
- W2769951627 hasConceptScore W2769951627C94412978 @default.
- W2769951627 hasLocation W27699516271 @default.
- W2769951627 hasLocation W27699516272 @default.
- W2769951627 hasOpenAccess W2769951627 @default.
- W2769951627 hasPrimaryLocation W27699516271 @default.
- W2769951627 hasRelatedWork W1964280200 @default.
- W2769951627 hasRelatedWork W1969561314 @default.
- W2769951627 hasRelatedWork W2039388619 @default.