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- W2770091563 abstract "An enantioselective approach to substituted indolizidine and quinolizidine frameworks has been developed. Key steps of the synthesis are the enantioselective, palladium-catalyzed N-allylation of an imide, the nucleophilic allylation of an acyliminium ion and a ring closing metathesis. This general strategy has been applied to the synthesis of indolizidine peptide mimics, starting from a chiral imide derived from l-aspartic acid. It was observed that the preexisting stereogenic center of this substrate has a moderate influence on the stereoselectivity of the electrophilic allylation, which is mainly determined by the sense of chirality of the catalyst." @default.
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- W2770091563 date "2018-01-01" @default.
- W2770091563 modified "2023-09-26" @default.
- W2770091563 title "Enantioselective approach to indolizidine and quinolizidine scaffolds. Application to the synthesis of peptide mimics" @default.
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- W2770091563 doi "https://doi.org/10.1016/j.tet.2017.11.042" @default.
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