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- W2770479529 abstract "Inverse opals made by polymerizing vinyl monomers inside a colloidal crystal have lattice dimensions that are contracted relative to the original hard template. This effect was studied in order to investigate the possibility of making double replicas of varying pore sizes from different materials, and to gain a better understanding of the polymer contraction behavior during replication. The degree of lattice contraction was measured using colloidal crystal films formed from silica spheres with diameters in the range 33–225 nm, and polymers pEDMA [poly(1,2-ethanediol dimethacrylate)], pDVB [poly(divinylbenzene)], pHDMA [poly(1,6-hexanediol dimethacrylate)], pBDMA [poly(1,4-butanediol dimethacrylate)], and a 5:4 copolymer mixture of pEDMA/pDVB. The degree of lattice contraction depended on the alkyl chain length of the monomer, as well as the degree of cross-linking, with up to 32% contraction observed for pEDMA when the silica template was removed. However, filling the polymer inverse opals with silica or titania returned the lattice spacing closer to its original size, an effect that can be rationalized in terms of the driving forces for contraction. Double replication of both single-component and binary silica colloidal crystals therefore generated silica and titania replicas of the original lattice. Thus, double replication provides a pathway for accessing periodic structures that are difficult to synthesize directly from materials such as titania." @default.
- W2770479529 created "2017-12-04" @default.
- W2770479529 creator A5046246087 @default.
- W2770479529 creator A5067936392 @default.
- W2770479529 date "2017-11-21" @default.
- W2770479529 modified "2023-10-18" @default.
- W2770479529 title "Double Replication of Silica Colloidal Crystal Films" @default.
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- W2770479529 doi "https://doi.org/10.1021/acsami.7b12662" @default.
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