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• W2770617242 abstract "The versatility of MOFs as highly porous Lewis acidic supports for precious metal nanoparticles has been exploited for one-pot tandem reductive amination catalysis. MIL-101(Cr) loaded with Pd nanoparticles ca. 3 nm in size at 0.2-1 wt% has been used to catalyse the reaction of 4'-fluoroacetophenone with benzylamine under 10 bar of H2 to give the secondary amine, 4'-fluoro-α-methyl-N-phenylmethylbenzenemethanamine. For the highest Pd loading, major hydrogenolysis of the secondary amine occurs in a second tandem reaction, but by changing the ratio of Pd to Lewis acidic Cr3+ active sites it is possible to tune the catalytic selectivity to the desired 2° amine product. An empirical kinetic analysis was performed to demonstrate this active site complementarity." @default.
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• W2770617242 date "2017-11-27" @default.
• W2770617242 modified "2023-09-26" @default.
• W2770617242 title "Tuning Pd-nanoparticle@MIL-101(Cr) Catalysts for Tandem Reductive Amination" @default.
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• W2770617242 doi "https://doi.org/10.1007/s10562-017-2208-0" @default.
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