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• W2771541112 startingPage "11341" @default.
• W2771541112 abstract "Abstract In this article, we report four pyridyl‐pyrazolyl based polynuclear cluster complexes with Ln 8 {Ln=[Gd III 8 (μ 3 ‐OH) 4 (L 1 ) 4 (DEA) 4 Cl 4 ](DMF) 2 (MeOH)( 1) , [Ho III 8 (μ 3 ‐OH) 4 (L 1 ) 4 (DEA) 4 Cl 4 ]( 2) , [Er III 8 (μ 3 ‐OH) 4 (L 1 ) 4 (DEA) 4 Cl 4 ](DMF)(MeOH)(H 2 O)( 3 ), [Yb III 8 (μ 3 ‐OH) 4 (L 1 ) 4 (DEA) 4 Cl 4 ](DMF)(MeOH)( 4 ) [DEA = Diethanolamine] cores. The impetus for this study was to explore the magnetic behaviour of lanthanide ions which are often ignored or overlooked. X‐ray crystal analysis show that these complexes are isostructural and exhibit an interesting butterfly like topology. The semi‐rigidity and asymmetric nature of the ligand led to different coordination environment around the metal centres. The lanthanide ions adopt two types of geometry, a bicapped trigonal prism and a distorted square antiprismatic geometry around the metal center. Such dissimilar coordination environments around the lanthanide centre can have profound effects on their magnetic behaviour. Indeed, the magnetic measurements revealed significant magnetocaloric effect for octanuclear gadolinium complex 1 with magnetic entropy change (−ΔS m ) of 31.4 J kg −1 K −1 for ΔH = 9 T at T = 3 K whereas Er analogue complex 3 displayed SMM behavior." @default.
• W2771541112 created "2017-12-22" @default.
• W2771541112 creator A5001608666 @default.
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• W2771541112 creator A5086092354 @default.
• W2771541112 date "2017-12-01" @default.
• W2771541112 modified "2023-09-27" @default.
• W2771541112 title "Ln₈ (Ln= Gd, Ho, Er, Yb) Butterfly Core-Exhibiting Magnetocaloric Effect and Field-Induced SMM Behavior for Er Analouge" @default.
• W2771541112 cites W1631025994 @default.
• W2771541112 cites W1725458513 @default.
• W2771541112 cites W1779354773 @default.
• W2771541112 cites W1790298317 @default.
• W2771541112 cites W1798747635 @default.
• W2771541112 cites W1844841953 @default.
• W2771541112 cites W1874636596 @default.
• W2771541112 cites W1963754464 @default.
• W2771541112 cites W1964488262 @default.
• W2771541112 cites W1968984308 @default.
• W2771541112 cites W1974094532 @default.
• W2771541112 cites W1978239898 @default.
• W2771541112 cites W1978964278 @default.
• W2771541112 cites W1979814481 @default.
• W2771541112 cites W1980049034 @default.
• W2771541112 cites W1981752765 @default.
• W2771541112 cites W1984044268 @default.
• W2771541112 cites W1991980803 @default.
• W2771541112 cites W1992069917 @default.
• W2771541112 cites W1993454278 @default.
• W2771541112 cites W1996104247 @default.
• W2771541112 cites W1999514087 @default.
• W2771541112 cites W2002623242 @default.
• W2771541112 cites W2002702348 @default.
• W2771541112 cites W2007563679 @default.
• W2771541112 cites W2012492137 @default.
• W2771541112 cites W2020442481 @default.
• W2771541112 cites W2020779890 @default.
• W2771541112 cites W2025508459 @default.
• W2771541112 cites W2028517136 @default.
• W2771541112 cites W2028728264 @default.
• W2771541112 cites W2033673475 @default.
• W2771541112 cites W2036613846 @default.
• W2771541112 cites W2037794270 @default.
• W2771541112 cites W2040650446 @default.
• W2771541112 cites W2042367197 @default.
• W2771541112 cites W2045930046 @default.
• W2771541112 cites W2047771713 @default.
• W2771541112 cites W2056988666 @default.
• W2771541112 cites W2058765331 @default.
• W2771541112 cites W2061616762 @default.
• W2771541112 cites W2062280884 @default.
• W2771541112 cites W2065237280 @default.
• W2771541112 cites W2070150426 @default.
• W2771541112 cites W2075010462 @default.
• W2771541112 cites W2080192187 @default.
• W2771541112 cites W2082881452 @default.
• W2771541112 cites W2086252731 @default.
• W2771541112 cites W2088210228 @default.
• W2771541112 cites W2099022855 @default.
• W2771541112 cites W2103827051 @default.
• W2771541112 cites W2106321593 @default.
• W2771541112 cites W2110424924 @default.
• W2771541112 cites W2110946497 @default.
• W2771541112 cites W2116195309 @default.
• W2771541112 cites W2119821378 @default.
• W2771541112 cites W2122391392 @default.
• W2771541112 cites W2130574055 @default.
• W2771541112 cites W2140284801 @default.
• W2771541112 cites W2145160897 @default.
• W2771541112 cites W2145776938 @default.
• W2771541112 cites W2150106365 @default.
• W2771541112 cites W2156486914 @default.
• W2771541112 cites W2159995865 @default.
• W2771541112 cites W2164322591 @default.
• W2771541112 cites W2172682873 @default.
• W2771541112 cites W2172909034 @default.
• W2771541112 cites W2262205891 @default.
• W2771541112 cites W2317453827 @default.
• W2771541112 cites W2321928674 @default.
• W2771541112 cites W2325431284 @default.
• W2771541112 cites W2326838895 @default.
• W2771541112 cites W2326862334 @default.
• W2771541112 cites W2330501265 @default.
• W2771541112 cites W2330743126 @default.
• W2771541112 cites W2332200090 @default.
• W2771541112 cites W2332373424 @default.
• W2771541112 cites W2332402427 @default.
• W2771541112 cites W2511639994 @default.
• W2771541112 cites W2621844366 @default.
• W2771541112 cites W3098018236 @default.
• W2771541112 doi "https://doi.org/10.1002/slct.201701905" @default.
• W2771541112 hasPublicationYear "2017" @default.
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