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- W2771570011 abstract "This thesis work deals with an understanding of the versatile roles of phosphonium ionic liquids (ILs) as nanostructuration and interfacial agents for the fluorinated polymer matrix, i.e.,poly(vinylidene fluoride-chlorotrifluoroethylene) (P(VDF-CTFE)). In this context, two phosphonium ILs with different functionalities in steric hindrance and extra dipolar groups are firstly incorporated in P(VDF-CTFE) matrix to prepare polymer films. The crystalline phase structure, dispersion morphology and crystallization behavior are finely characterized with the goal of providing a full and deep understanding of the versatile and tunable nanostructuration effect of phosphonium ILs. Subsequently, in order to elucidate the mechanism of interfacial influence of IL, a fluorinated phosphonium IL with a cation structure combining three phenyls and a short fluorinated chain is added on the surface of graphene oxide (GO) and reduced graphene oxide (rGO), making them as functional nanofillers to be incorporated into P(VDF-CTFE) matrix. Thus,P(VDF-CTFE)/graphene composite films with different filler contents are prepared in order to investigate the mechanism of interfacial interaction and its influence on the composite films, such as crystalline phase structure, crystallization behavior, chain segmental relaxation behavior, dispersion morphology and the final dielectric properties." @default.
- W2771570011 created "2017-12-22" @default.
- W2771570011 creator A5055498292 @default.
- W2771570011 date "2016-07-20" @default.
- W2771570011 modified "2023-09-28" @default.
- W2771570011 title "Phosphonium ionic liquids : Versatile nanostructuration and interfacial agents for poly(vinylidene fluoride-chlorotrifluoroethylene)" @default.
- W2771570011 hasPublicationYear "2016" @default.
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