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- W2771783706 abstract "Two strategies based on kinetic resolution(s) of chiral alanes and providing enantioenriched syn homoallylamines are reported. The first implies a single kinetic resolution of the alane using camphor; the second requires two sequential kinetic resolutions using the synergistic combination of (−)-camphor/(R)-tert-butylsulfinamide-derived imines. This syn selectivity, specific to the use of allyaluminum, opens the way to the preparation of valuable building blocks as illustrated by the synthesis of (+)-epilupinamine." @default.
- W2771783706 created "2017-12-22" @default.
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- W2771783706 date "2017-12-06" @default.
- W2771783706 modified "2023-10-06" @default.
- W2771783706 title "Single or Synergistic Kinetic Resolutions of Chiral Allylalanes: Two Complementary Routes for the Asymmetric Synthesis of <i>Syn</i> Homoallylamines" @default.
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- W2771783706 doi "https://doi.org/10.1021/acs.orglett.7b03455" @default.
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