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- W2771817459 abstract "This communication describes a synthetic study of the originally proposed structure of mycalol ( 1 ) and the total synthesis of the actual structure of the anticancer marine natural product mycalol ( 2 ). The total synthesis of the originally proposed structure of mycalol ( 1 ) was targeted by a late‐stage asymmetric dihydroxylation, which resulted in an inseparable mixture of diastereomers. Thus a new strategy was developed for the total synthesis of the revised structure of mycalol ( 2 ); all the stereocentres except the C‐2′‐OH were created in an asymmetric fashion by using a Maruoka allylation, a Noyori asymmetric reduction, and an asymmetric alkynylation." @default.
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- W2771817459 date "2018-01-22" @default.
- W2771817459 modified "2023-09-29" @default.
- W2771817459 title "Total Synthesis of the Anticancer Marine Natural Product Mycalol" @default.
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- W2771817459 doi "https://doi.org/10.1002/ejoc.201701562" @default.
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