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- W27720234 abstract "The aggregation of meso-tetrakis(4-hydroxyphenyl)porphyrin (H2THPP) in dimethylformamide (DMF)-water solution and in DMF-chloroform solution was studied by UV-vis absorption spectroscopy. The red shift of Soret band indicates the formation of J-type aggregates of H2THPP in these two solutions. However, different shift extent of Soret band, 12 nm in DMF-water solution and 32 nm in DMF-chloroform solution, implies structural difference between these two J-type aggregates. The hydrogen bond between hydroxyl group and N-H bonds in porphyrin ring is thought as the main cause to the formation of J-type aggregate in DMFchloroform solution, whereas the π-σ interaction between two adjacent porphyrin cores is thought as the main cause of the formation of J-type aggregate in DMF-water solution" @default.
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- W27720234 date "2005-01-01" @default.
- W27720234 modified "2023-09-23" @default.
- W27720234 title "Different J-Type Aggregates of meso-Tetrakis （4-hydroxyphenyl） porphyrin （H2THPP） Formed in Different Solvents" @default.
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