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• W2772049769 abstract "Abstract We describe an efficient convergent synthesis of vitamin D 3 metabolites and analogues. The synthetic strategy relies on a tandem Pd‐catalyzed A‐ring closure and Suzuki–Miyaura coupling to the CD‐side chain component to set directly the vitamin D triene system under protic conditions. This strategy enables rapid access to vitamin D 3 and 3‐epi‐vitamin D 3 metabolites and analogues modified at the side chain for biological evaluation and structural and metabolic studies." @default.
• W2772049769 created "2017-12-22" @default.
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• W2772049769 date "2018-02-06" @default.
• W2772049769 modified "2023-10-16" @default.
• W2772049769 title "Stereoselective Palladium-Catalyzed Approach to Vitamin D₃ Derivatives in Protic Medium" @default.
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• W2772049769 doi "https://doi.org/10.1002/chem.201705656" @default.
• W2772049769 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29239492" @default.
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