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- W2772706715 abstract "Photochemical reaction of trans-2,6-diaryl-4H-spiro[cyclohexane-1,2′-indene]-1′,3′,4-triones gives rise to the formation of the ylidenephthalide derivatives as previously observed for 2,2-disubstituted 1,3-indandiones. In contrast, the respective cis-isomers afford different products originating from the unprecedented reversible cyclohexanone cycle breaking (photo-induced retro-Michael reaction). The difference between the reaction pathways does not depend on the irradiation wavelengths or the light source power and is observed both in solution and solid state." @default.
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- W2772706715 date "2018-01-01" @default.
- W2772706715 modified "2023-09-25" @default.
- W2772706715 title "Stereochemistry in control of photochemical reactivity: 2,6-Diaryl-4 H -spiro[cyclohexane-1,2′-indene]-1′,3′,4-triones" @default.
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- W2772706715 doi "https://doi.org/10.1016/j.tet.2017.12.014" @default.
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