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• W2773682022 endingPage "18193" @default.
• W2773682022 startingPage "18190" @default.
• W2773682022 abstract "The insertion of 1,1-diphenylethylene into the Mg–Mg bond of two magnesium(I) dimers, [(ArNacnac)Mg−]2 (Ar = C6H2Me3-2,4,6 (Mes); C6H3Et2-2,6 (Dep)), yielding 1,2-dimagnesioethane products, [{(ArNacnac)Mg}2(μ-CH2CPh2)], is described. These reactions are readily reversible at room temperature and thus represent the first examples of room-temperature reversible redox processes for s-block metal complexes. The 1,2-dimagnesioethane products are highly activated magnesium alkyls and show unprecedented, uncatalyzed reactivity toward H2, CO, and ethylene. Computational studies have investigated the mechanisms of all presented reaction types." @default.
• W2773682022 created "2017-12-22" @default.
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• W2773682022 date "2017-12-08" @default.
• W2773682022 modified "2023-10-16" @default.
• W2773682022 title "Reversible Insertion of a C═C Bond into Magnesium(I) Dimers: Generation of Highly Active 1,2-Dimagnesioethane Compounds" @default.
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• W2773682022 doi "https://doi.org/10.1021/jacs.7b11368" @default.
• W2773682022 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29206455" @default.
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