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- W2773761574 abstract "An overview is given of recent advances in the kinetic theory and thermodynamics of reversible copolymerization processes. Remarkably, the thermodynamic entropy production depends not only on the free enthalpy of formation, but also on sequence disorder. Accordingly, copolymer chains may grow either in a favorable free-enthalpy landscape or by the entropic effect of sequence disorder in an adverse free-enthalpy landscape. This result has several consequences. In particular, the ceiling temperature for the copolymerization of two species is typically larger than the ceiling temperatures of the pure polymers grown with the same concentration for either species. In addition, the sequence disorder generated during copolymerization can exert a mechanical force under specific conditions. Furthermore, the kinetic equations describing the reversible copolymerization of Bernoulli or Markov chains can be exactly solved in the regimes of steady growth if the monomeric concentrations remain constant in time, generalizing the Mayo-Lewis theory beyond the fully irreversible regime. Similar results hold for reversible template-directed copolymerization." @default.
- W2773761574 created "2017-12-22" @default.
- W2773761574 creator A5065368261 @default.
- W2773761574 date "2017-12-04" @default.
- W2773761574 modified "2023-10-17" @default.
- W2773761574 title "Kinetics and Thermodynamics of Sequence Regulation" @default.
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- W2773761574 doi "https://doi.org/10.1002/9783527806096.ch2" @default.
- W2773761574 hasPublicationYear "2017" @default.
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