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• W2773779968 abstract "Delayed-acquisition, which is a common technique for improving spectral resolution in Fourier transform based spectroscopies, typically relies upon differences in T2 relaxation rates that are often due to underlying differences in dynamics and/or complexities of the spin systems being studied. After an acquisition delay, the broad signals from fast T2-relaxing species are more suppressed relative to the sharp signals from slow T2-relaxing species. In this paper, an alternative source of differential “dephasing” under delayed-acquisition is demonstrated that is based solely upon the mathematical properties of the line shape and is independent of the underlying spin dynamics and/or complexity. Signals associated with frequencies where the line shape either changes sharply and/or is non-differentiable at some finite order dephase at a much slower rate than those signals associated with frequencies where the line shape is smooth. Experiments employing delayed-acquisition to study interfaces in biphasic samples, to measure spatially-dependent longitudinal relaxation, and to highlight sharp features in NMR spectra are presented." @default.
• W2773779968 created "2017-12-22" @default.
• W2773779968 creator A5053738993 @default.
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• W2773779968 date "2018-02-01" @default.
• W2773779968 modified "2023-09-27" @default.
• W2773779968 title "Enhancing the detection of edges and non-differentiable points in an NMR spectrum using delayed-acquisition" @default.
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• W2773779968 doi "https://doi.org/10.1016/j.jmr.2017.12.012" @default.
• W2773779968 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29274937" @default.
• W2773779968 hasPublicationYear "2018" @default.
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