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• W2773987825 endingPage "1284" @default.
• W2773987825 startingPage "1273" @default.
• W2773987825 abstract "Carbon and nitrogen species on the surface of carbon nanotubes (N-CNTs) and nanofibers (N-CNFs) were studied by X-ray absorption (XAS) and photoelectron spectroscopy (PES) including the analysis of nitrogen distribution over the depth of materials. The study was performed with a series of bamboo-like carbon nanotubes and nanofibers having the platelet-like and herringbone-like morphology. It was shown that the main nitrogen species in the composition of the studied materials are pyridine, pyrrole (and/or amino groups), graphite-like and oxidized states of nitrogen. In distinction to nanofibers, the bamboo-like nanotubes additionally contain molecular nitrogen encapsulated in the internal hollows. Spectral data for different depths of analysis were obtained by varying the energy of incident radiation. Such an approach revealed that N-CNTs are characterized by non-uniform distribution of chemically bound nitrogen species. Thus, nitrogen enrichment was observed on the external surface and in the internal arches of carbon nanotubes. Nitrogen enrichment in the subsurface region was found for N-CNFs, whereas the full depth analysis of N-distribution was limited by a large diameter of nanofibers." @default.
• W2773987825 created "2017-12-22" @default.
• W2773987825 creator A5002216878 @default.
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• W2773987825 date "2018-03-01" @default.
• W2773987825 modified "2023-10-01" @default.
• W2773987825 title "Spectroscopic study of nitrogen distribution in N-doped carbon nanotubes and nanofibers synthesized by catalytic ethylene-ammonia decomposition" @default.
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• W2773987825 doi "https://doi.org/10.1016/j.apsusc.2017.11.244" @default.
• W2773987825 hasPublicationYear "2018" @default.
• W2773987825 type Work @default.
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