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• W2774366871 abstract "An asymmetric Ni-catalyzed reductive cross-coupling has been developed to prepare enantioenriched allylic silanes. This enantioselective reductive alkenylation proceeds under mild conditions and exhibits good functional group tolerance. The chiral allylic silanes prepared here undergo a variety of stereospecific transformations, including intramolecular Hosomi-Sakurai reactions, to set vicinal stereogenic centers with excellent transfer of chirality." @default.
• W2774366871 created "2017-12-22" @default.
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• W2774366871 date "2017-12-20" @default.
• W2774366871 modified "2023-10-14" @default.
• W2774366871 title "Synthesis of Enantioenriched Allylic Silanes via Nickel-Catalyzed Reductive Cross-Coupling" @default.
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• W2774366871 doi "https://doi.org/10.1021/jacs.7b11707" @default.
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