FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2774534421> ?p ?o ?g. }

• W2774534421 endingPage "431" @default.
• W2774534421 startingPage "424" @default.
• W2774534421 abstract "The mechanism of the reaction of dichlorvos through hydrolysis reactions and through the reaction with polysulfide (Sn2–) and thiophenolate (PhS–) was investigated by proton nuclear magnetic resonance (1H NMR). The study confirmed product identities of an organophosphorus insecticide reacting with reduced sulfur species using 1H NMR in oxygen sensitive solutions. The experiments of dichlorvos with polysulfide led to the detection of a previously undetected product. The thiophenolate experiments were further advanced to investigate second-order rate kinetics using an internal standard. The experiments provide new evidence for a nucleophilic attack by the reduced sulfur species at the methoxy carbon of dichlorvos. In addition, the observation of in situ reaction dynamics illustrates the applicability of 1H NMR spectroscopy toward kinetic investigations in environmental science." @default.
• W2774534421 created "2017-12-22" @default.
• W2774534421 creator A5034276889 @default.
• W2774534421 creator A5073373934 @default.
• W2774534421 creator A5088585271 @default.
• W2774534421 date "2018-01-03" @default.
• W2774534421 modified "2023-09-25" @default.
• W2774534421 title "Investigation of the Nucleophilic Attack of Dichlorvos by Reduced Sulfur Species Using ¹H NMR" @default.
• W2774534421 cites W1022590300 @default.
• W2774534421 cites W1976137128 @default.
• W2774534421 cites W1981477866 @default.
• W2774534421 cites W1983126103 @default.
• W2774534421 cites W1984330388 @default.
• W2774534421 cites W2007081221 @default.
• W2774534421 cites W2021305921 @default.
• W2774534421 cites W2024248473 @default.
• W2774534421 cites W2034022103 @default.
• W2774534421 cites W2035455585 @default.
• W2774534421 cites W2036152043 @default.
• W2774534421 cites W2039750430 @default.
• W2774534421 cites W2041720480 @default.
• W2774534421 cites W2048322679 @default.
• W2774534421 cites W2052539619 @default.
• W2774534421 cites W2064485679 @default.
• W2774534421 cites W2066560964 @default.
• W2774534421 cites W2070873877 @default.
• W2774534421 cites W2073914652 @default.
• W2774534421 cites W2074102476 @default.
• W2774534421 cites W2078694684 @default.
• W2774534421 cites W2088308171 @default.
• W2774534421 cites W2136180547 @default.
• W2774534421 cites W2155674861 @default.
• W2774534421 cites W2480812939 @default.
• W2774534421 cites W2503332022 @default.
• W2774534421 doi "https://doi.org/10.1021/acs.jafc.7b04749" @default.
• W2774534421 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29224357" @default.
• W2774534421 hasPublicationYear "2018" @default.
• W2774534421 type Work @default.
• W2774534421 sameAs 2774534421 @default.
• W2774534421 citedByCount "5" @default.
• W2774534421 countsByYear W27745344212019 @default.
• W2774534421 countsByYear W27745344212020 @default.
• W2774534421 countsByYear W27745344212021 @default.
• W2774534421 countsByYear W27745344212022 @default.
• W2774534421 crossrefType "journal-article" @default.
• W2774534421 hasAuthorship W2774534421A5034276889 @default.
• W2774534421 hasAuthorship W2774534421A5073373934 @default.
• W2774534421 hasAuthorship W2774534421A5088585271 @default.
• W2774534421 hasConcept C103319777 @default.
• W2774534421 hasConcept C135731615 @default.
• W2774534421 hasConcept C147789679 @default.
• W2774534421 hasConcept C161176658 @default.
• W2774534421 hasConcept C161790260 @default.
• W2774534421 hasConcept C163111631 @default.
• W2774534421 hasConcept C17525397 @default.
• W2774534421 hasConcept C178790620 @default.
• W2774534421 hasConcept C178907741 @default.
• W2774534421 hasConcept C185592680 @default.
• W2774534421 hasConcept C2777379467 @default.
• W2774534421 hasConcept C2778359560 @default.
• W2774534421 hasConcept C518881349 @default.
• W2774534421 hasConcept C6557445 @default.
• W2774534421 hasConcept C66974803 @default.
• W2774534421 hasConcept C68801617 @default.
• W2774534421 hasConcept C86803240 @default.
• W2774534421 hasConcept C94412978 @default.
• W2774534421 hasConcept C96765332 @default.
• W2774534421 hasConceptScore W2774534421C103319777 @default.
• W2774534421 hasConceptScore W2774534421C135731615 @default.
• W2774534421 hasConceptScore W2774534421C147789679 @default.
• W2774534421 hasConceptScore W2774534421C161176658 @default.
• W2774534421 hasConceptScore W2774534421C161790260 @default.
• W2774534421 hasConceptScore W2774534421C163111631 @default.
• W2774534421 hasConceptScore W2774534421C17525397 @default.
• W2774534421 hasConceptScore W2774534421C178790620 @default.
• W2774534421 hasConceptScore W2774534421C178907741 @default.
• W2774534421 hasConceptScore W2774534421C185592680 @default.
• W2774534421 hasConceptScore W2774534421C2777379467 @default.
• W2774534421 hasConceptScore W2774534421C2778359560 @default.
• W2774534421 hasConceptScore W2774534421C518881349 @default.
• W2774534421 hasConceptScore W2774534421C6557445 @default.
• W2774534421 hasConceptScore W2774534421C66974803 @default.
• W2774534421 hasConceptScore W2774534421C68801617 @default.
• W2774534421 hasConceptScore W2774534421C86803240 @default.
• W2774534421 hasConceptScore W2774534421C94412978 @default.
• W2774534421 hasConceptScore W2774534421C96765332 @default.
• W2774534421 hasIssue "2" @default.
• W2774534421 hasLocation W27745344211 @default.
• W2774534421 hasLocation W27745344212 @default.
• W2774534421 hasOpenAccess W2774534421 @default.
• W2774534421 hasPrimaryLocation W27745344211 @default.
• W2774534421 hasRelatedWork W1982367910 @default.
• W2774534421 hasRelatedWork W2074102476 @default.
• W2774534421 hasRelatedWork W2096615669 @default.
• W2774534421 hasRelatedWork W2212102046 @default.
• W2774534421 hasRelatedWork W2336424505 @default.
• W2774534421 hasRelatedWork W2354327617 @default.
• W2774534421 hasRelatedWork W2371361369 @default.

• next