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- W2775343042 abstract "The paper presents results of studies of the conductivity of aliovalent substitution solid solutions, which are formed in the system (1−x)PbF 2 — xSmF 3 — SnF 2 in the concentration range 0 4 . At a low aliovalent substituent content (x ≤ 0,07), the conductivity of the synthesized fluorides is by an order of magnitude lower than that of β-PbSnF 4 . At a higer content, it increases and reaches the largest values at x = 0.15. The fluorine anions in the synthesized samples of solid solutions are in three structurally nonequivalent positions, which differ in local environment and the nature of the M-F bond. The conductivity of the synthesized samples is provided by highly mobile interstitial fluorine anions." @default.
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- W2775343042 date "2017-09-01" @default.
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- W2775343042 title "Electrical conductivity of aliovalent substitution solid solution Pb<inf>1−x</inf>Sm<inf>x</inf>SnF<inf>4+x</inf>" @default.
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- W2775343042 doi "https://doi.org/10.1109/nap.2017.8190348" @default.
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